
TAKAGI Shinsuke
教授
髙木 慎介 タカギ シンスケ たかぎ しんすけ
プロフィール
最終学歴・学位
博士(工学)
専門・研究分野
光化学、ナノ構造化学、ポルフィリンの化学、無機有機複合体の化学、粘土科学
研究
研究テーマ
理想的なエネルギー変換反応である人工光合成を実現できれば、都市の環境・エネルギー問題に大きく貢献することができます。
環境化学の視点から、環境に優しい粘土鉱物などの天然材料を用いた、人工光合成、機能性色素材料に関する研究を行っています。
金属ポルフィリンによる人工光合成型物質変換反応の開発
ナノ層状粒子ーポルフィリン複合体におけるナノ構造制御
粘土鉱物ーポルフィリン複合体による光捕集モデルの構築
研究キーワード
光エネルギー、人工光合成、人工光捕集系、ポルフィリン、光、エポキシ化、光合成、粘土、ナノシート、無機有機複合体
詳細情報
"Surface-fixation Induced Emission" in Handbook of Aggregation-Induced Emission
Yohei Ishida, Shinsuke Takagi
Editor(s):Youhong Tang, Ben Zhong Tang
2022 John Wiley & Sons Ltd.
"Photo-cyclization, Photo-ring opening and Thermo-ring opening Reaction of Cationic Diarylethene Adsorbed on the Clay Nanosheet Surface"
Kyosuke Arakawa, Tetsuya Shimada, Tamao Ishida, ShinsukeTakagi
Colloids and Surfaces A: Physicochemical and Engineering Aspects, Available online 11 November 2022, 130537
"Enhancement effect of strong metal-support interaction (SMSI) on the catalytic activity of substituted-hydroxyapatite supported Au clusters"
Akihiro Nakayama, Ryusei Sodenaga, Yuvaraj Gangarajula, Ayako Taketoshi, Toru Murayama, Tetsuo Honma, Norihito Sakaguchi, Tetsuya Shimada, Shinsuke Takagi, Masatake Haruta, Botao Qiao, Junhu Wang,Tamao Ishida
Journal of Catalysis Volume 410, June 2022, Pages 194-205.
"Photochemical hydrogen evolution using Pt/titania nanosheet catalysts prepared by chemical-reduction and photo-deposition methods"
Hosei Takimoto, Yugo Hirade, Tetsuya Shimada, Tamao Ishida and Shinsuke Takagi
Results in Chemistry 2022, 4, 100271. https://doi.org/10.1016/j.rechem.2021.100271
"Precise evaluation of adsorption behavior of cationic porphyrin on monolayer of perovskite-type niobia nanosheet by absorption spectroscopy"
Momoka Oshima, Keito Sano, Yugo Hirade, Ryosuke Nakazato, Tamao Ishida, Tetsuya Shimada, Shinsuke Takagi
Journal of Physics and Chemistry of Solids 2022, 161, 110423. https://doi.org/10.1016/j.jpcs.2021.110423
・光化学協会「光化学」
プリフィス"カーボンニュートラルと光化学"
光化学, 2021, 52, 45.
・日本化学会「低次元系光機 能材料研究会 ニュースレター」
"なぜ化学を研究するのか"
低次元系光機能材料研究会ニュースレター, 2021, 24, 7-13.
・"Estimation of adsorption distribution of di-cationic porphyrin on anionic nanosheet surface using self-fluorescence quenching as a probe"
Yutaka Ohsaki, Ryohei Shibatani, Tetsuya Shimada, Tamao Ishida, Shinsuke Takagi
Chem. Lett. 2021, in press.
・"Effects of Surface Charge Density of Clay Minerals on Surface-fixation Induced Emission (S-FIE) of Acridinium Derivatives"
Shinsuke Takagi,* et. al.
ACS Omega 2021, 6, 33, 21702–21708. Link
・"“In-water” Dehydration reaction of Aromatic Diol on Inorganic Surface"
Shinsuke Takagi,* et. al.
Langmuir 2021, 37, 11978–11985. Link
・"Acid-base equilibria of axial ligand and peripheral pyridyl group with stepwise formation of nine species of aluminum (III) tera (4-pyridyl) porphyrin"
Siby Mathew, AbinSebastian, Fazalurahman Kuttassery, Shinsuke Takagi, Hiroshi Tachibana, Haruo Inoue
Inorganica Chimica Acta, 2021, 526, 120529.
・"UNIQUE NON SELF-LUMINESCENCE QUENCHING BEHAVIOR OF CATIONIC Pt(IV)PORPHYRIN ON CLAY SURFACE"
Shinsuke Takagi,* et. al.
Clay Science, in press.
・"Adsorption and absorption behavior of cationic porphyrin on titania and clay nanosheets"
Shinsuke Takagi,* et. al.
Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2021, 624, 126747.
・"Dye-sensitized Hydrogen Production by Porphyrin/Rh-doped-Titania-Nanosheet Complex"
Shinsuke Takagi,* et. al.
Bulletin of the Chemical Society of Japan, 2021, 94, 937-942.
・"Effect of Li ions Doping into p-type Semiconductor NiO as a Hole Injection/Transfer Medium in the CO2 Reduction Sensitized/Catalyzed by Zn-porphyrin/Re-complex upon Visible Light Irradiation"
Shinsuke Takagi,* et. al.
Res. Chem. Intermed., 2021, 47, 269-285.
・"Adsorption Orientation Control of Di-cationic Porphyrin on Titania-nanosheet"
Tetrahedron Letters, 2020, 61, 152494.
・"Optically Transparent Colloidal Dispersion of TiO2 Nanoparticles Storable for longer than One year Prepared by Sol/Gel Progressive Hydrolysis/Condensation"
ACS Applied Material and Interface, 2020, 12, 44743-44753.
・Dyes and Photoactive Molecules in Microporous Systems、 2020 Springer Natureが発刊されました。
Tuning emission properties by dye encapsulation into layered silicates を執筆しています。
・ "Two-electron oxidation of water to form hydrogen peroxide initiated by one-electron oxidation of Tin (IV)-porphyrins"
Journal of Photochemistry & Photobiology, A: Chemistry, 2020, 401, 112732.
・"Anisotropic energy transfer in the clay-porphyrin layered system with environment-responsiveness"
Physical Chemistry Chemical Physics, 2020, 22, 14261-14267.
・ "Adsorption Behavior of Mono-cationic Acridinium Derivatives on Clay Surface"
RSC Advances, 2020, 10, 21360 - 21368
・"Unique enzyme activity of peroxidase on the clay-nanosheet"
Langmuir 2020, 36, 29, 8384–8388
・(島根大学 藤村卓也先生との共同研究によるものです)
"Adsorption behavior of mono-cationic pyridinium salts on the clay surface"
doi:10.1246/bcsj.20200100
・(島根大学 藤村卓也先生、笹井亮先生との共同研究によるものです)
"Photoreduction of Methylviologen in Saponite Clay: Effect of Methylviologen Adsorption Density on the Reaction Efficiency"
https://doi.org/10.1007/s42860-019-00047-8
・特集/ナノテクノロジーの新展開・ナノシートとの複合化による強発光性材料の開発, S. Takagi, K. Arakawa, 化学工業誌, 2020, 71, 14-18.
・"Effect of clay surface on aldehyde-diol equilibrium"
Tetrahedron Letters, 2019, 60, 150986. DOI: 10.1016/j.tetlet.2019.150986
・ "Factors for the emission enhancement of dimidium in the specific medium such as DNA and clay surface"
Physical Chemistry Chemical Physics, 2019, 21, 22732 - 22739. DOI: 10.1039/C9CP03285A
Selected as inside cover article
・Reversed Micelles Formed by Polyfluorinated Surfactant II; the Properties of Core Water Phase in Reversed Micelle
Bulletin of the Chemical Society of Japan, doi:10.1246/bcsj.20190086
・ "Which Type of Clay Minerals Fix Cesium Ion Effectively? -Cavity-Charge Matching Effect- "
Physical Chemistry Chemical Physics, 2019, 21, 9352 - 9356. DOI: 10.1039/C9CP00457B
・"An Artificial Photosynthesis Model: Photochemical Reaction System with Efficient Light Harvesting Function on Inorganic Nanosheets"
Shinsuke Takagi,* et. al.
ACS Omega, 2018, 3 (12), pp 18563–18571
・Sebastian Nybin Remello, Fazalurahman Kuttassery, Siby Mathew, Arun Thomas, Daisuke Yamamoto, Yu Nabetani, Keito Sano, Hiroshi Tachibana and Haruo Inoue *
"Two-electron oxidation of water to form hydrogen peroxide catalysed by silicon-porphyrins"
Sustainable Energy Fuels, 2018, 2, 1966–1973.
・"How does the tin(IV)-insertion to porphyrins proceed in water at ambient temperature?: Re-investigation by time dependent 1H NMR and detection of intermediates"
Inorganica Chimica Acta 482 (2018) 914–924.
・"Adsorption and Emission Enhancement Behavior of 4,4-Bipyridine on Dispersed Montmorillonite Nano-sheets under Aqueous Conditions"
Shinsuke Takagi,* et. al.
・以下の論文がオンラインニュースサイトEurekAlert!に掲載されました!
Langmuir, 2018, 34 (12), pp 3572–3577.
・Chem. Lett.誌
" Efficient Electron Injection from Excited Porphyrin to Titania Nanosheet"
Shinsuke Takagi,* et. al.
・島根大学 藤村卓也先生、笹井亮先生との共同研究によるものです)
"Optical Humidity Sensing Using Transparent Hybrid Film Composed of Cationic Magnesium Porphyrin and Clay Mineral"
Shinsuke Takagi,* et. al.
・J. Phys. Chem. C
"Elucidation of the Adsorption Distribution of Cationic Porphyrin on the Inorganic Surface by Energy Transfer as a Molecular Ruler"
Shinsuke Takagi,* et. al.
・Langmuir誌(信州大学 岡田友彦先生との共同研究によるものです)
"Photoluminescence by Intercalation of a Fluorescent β?Diketone Dye into a Layered Silicate"
Langmuir, 2017, 33, 13515?13521.
・2017年8月 特許 第6183838号 異性化反応制御方法、及び異性体製造方法
・"Characterization of Dispersed Titania Nanosheet under Aqueous Conditions and its Complex Formation Behavior with Cationic Porphyrin"
Shinsuke Takagi,* et. al.
J. Photochem. Photobiol. A, 2017, 353, 597-601.
・"Highly Selective Photochemical Epoxidation of Cyclohexene Sensitized by Ru(II) Porphyrin-Clay Hybrid Catalyst"
Chem. Lett., 2017, 30, 128-129.
・2017年5月 Springer社 Inorganic Nanosheets and Nanosheet-Based Materials (Fundamentals and Applications of Two-Dimensional Systems, Editors: Nakato, Teruyuki, Kawamata, Jun, Takagi, Shinsuke (Eds.))
・2017年5月 化学と工業5月号の特集(相乗効果を産み出す層状構造)"層状無機化合物と光化学"(高木慎介
・2017年3月 日本化学会[CSJカレントレビュー25]二次元物質の科学 グラフェンなどの分子シートが生み出す新世界
・Langmuir誌
(新潟大学 由井樹人先生との共同研究によるものです)
"Light Energy Accumulation from Pyrene Derivative to Tris(bipyridine)ruthenium on Clay Surface"
Langmuir, 2017, 33, 3680-3684.
・Journal of Photochemistry and Photobiology A: Chemistry
(新潟大学 由井樹人先生との共同研究によるものです)
"Color Tuning of Cationic Pyrene Derivatives on Clay Nano-sheet: Retardation of Gradual Red Shift on Clay"
J. Photochem. Photobiol. A: Chem. 2017, 337, 112?117.
・Royal Society of Chemistry Physical Chemistry Chemical Physics 誌
(島根大学 笹井亮先生との共同研究によるものです)
"Photoinduced electron transfer in layer-by-layer thin solid films containing cobalt oxide nanosheets, porphyrin, and methylviologen"
R. Sasai, Y. Kato, W. Soontornchaiyakul, H. Usami, A. Masumori, W. Norimatsu, T. Fujimura, S. Takagi
Physical Chemistry Chemical Physics 2017, 19, 5611-5616.
・"Size-Matching Effect” in Cationic Porphyrin-Titania Nanosheet Complex"
Sonotani, Amane; Shimada, Tetsuya; Takagi, Shinsuke
Chemistry Letters 2017, 46, 499-501.
・Journal of Photochemistry and Photobiology A: Chemistry誌
(新潟大学 由井樹人先生との共同研究によるものです)
"Color Tuning of Cationic Pyrene Derivatives on Clay Nano-sheet: Retardation of Gradual Red Shift on Clay"
J. Photochem. Photobiol. A: Chem. 2017, in press.
・Physical Chemistry Chemical Physics 誌 (IF = 4.493)
"Photoinduced electron transfer in layer-by-layer thin solid films containing cobalt oxide nanosheets, porphyrin, and methylviologen"
R. Sasai, Y. Kato, W. Soontornchaiyakul, H. Usami, A. Masumori, W. Norimatsu, T. Fujimura, S. Takagi
Physical Chemistry Chemical Physics 2017, in press.
・"Size-Matching Effect” in Cationic Porphyrin-Titania Nanosheet Complex"
Shinsuke Takagi,* et. al.
Chemistry Letters 2017, 46, 499-501.
・Journal of Photochemistry and Photobiology A: Chemistry誌(Invited Feature Article)
"Unique Fluorescence Behavior of Dyes on the Clay Minerals Surface: Surface Fixation Induced Emission (S-FIE)"
Shinsuke Takagi,* et. al.
J. Photochem. Photobiol. A: Chem. 2017, 339, 67-79.
・"Energy Transfer among Three Dye Components in a Nanosheet?Dye Complex: An Approach to Evaluating the Performance of a Light-Harvesting System"
Shinsuke Takagi,* et. al.
J. Phys. Chem. C, 2017, in press.
・"Room Temperature Phosphorescence from a Guest Molecule Confined in Restrictive Space of an Organic?Inorganic Supramolecular Assembly"
Yohei Ishida, Tetsuya Shimada, Elamparuthi Ramasamy, Vaidhyanathan Ramamurthy* and Shinsuke Takagi*
Photochemical & Photobiological Sciences, 2016, 15, 959-963.
・"Supramolecular-Surface Photochemistry: Cascade Energy Transfer between Encapsulated Dyes Aligned on Clay Nano-sheet Surface"
Tsukamoto, Takamasa; Ramasamy , Elamparuthi ; Shimada, Tetsuya; Takagi, Shinsuke; Ramamurthy, Vaidhyanathan
Langmuir, 2016, 32, 2920.
・"Kinetic Analysis by Laser Flash Photolysis of Porphyrin Molecules’ Orientation Change at the Surface of Silicate Nanosheet"
Shinsuke Takagi,* et. al.
J, Phys. Chem. C, 2016, 120, 7428?7434
・"Photophysical Properties and Adsorption Behaviors of Novel Tri-Cationic Boron(III) Subporphyrin on Anionic Clay Surface"
Shinsuke Takagi,* et. al.
ACS Applied Materials & Interfaces, 2016, 8, 7522-7528.
・"Supramolecular-Surface Photochemistry: Sequential Energy and Electron Transfer in a Three-component System Aligned on a Clay Nanosheet"
Takuya Fujimura, Elamparuthi Ramasamy, Yohei Ishida, Tetsuya Shimada, Shinsuke Takagi*, Vaidhyanathan Ramamurthy*
Physical Chemistry Chemical Physics, 2016,18, 5404-5411.
(米国Miami大学 V. Ramamurthy先生、島根大学 藤村卓也先生との共同研究によるものです)
・"Emission amplification of Ru(bpy)32+ via energy transfer from pyrene derivatives on synthesized clay"
Journal of Photochemistry and Photobiology A: Chemistry 313 (2015) 9?14.
・"Dense Deposition of Gold Nano Clusters Utilizing a Porphyrin/Inorganic Layered Material Complex as the Template"
Shinsuke Takagi,* et. al.
Langmuir, 2015, 31, 9142?9147
・"The Artificial Light Harvesting System with Energy Migration Functionality in the Cationic Dyes / Inorganic Nano-sheet Complex"
Shinsuke Takagi,* et. al.
J. Phys. Chem. C, 2015, 119 (33), pp 18896?18902
・"Anisotropic Photochemical Energy Transfer in Clay / Porphyrin System Prepared by Size-matching effect and Langmuir-Blodgett Technique"
Shinsuke Takagi,* et. al.
Journal of Photochemistry and Photobiology A: Chemistry 2015, 313, 15?18.
・"Remarkable stimulation of emission quenching on a clay surface"
Sato, K., Matsubara, K., Hagiwara, S., Saito, K., Yagi, M., Takagi, S., Yui, T.
Langmuir 2015, 31, 27-31.
・"Photochemical Chlorination and Oxygenation Reaction of Cyclohexene Sensitized by Ga(III) Porphyrin-Clay Minerals System with High Durability and Usability"
T. Tsukamoto, T. Shimada, T. Shiragami, S. Takagi
Bulletin of the Chemical Society of Japan, 2015, 88, 578-583.
・"Structure resembling effect of clay surface on photochemical properties of meso-phenyl or pyridyl-substituted monocationic antimony(V) porphyrin derivatives"
RSC Advances, 2015, 5, 8479-8485.
・「光合成研究と産業応用最前線」(エヌ・ティー・エス) 部分執筆
・"Microstructures of Porphyrin/Viologen Monolayer on the Clay Surface: Segregation or Integration?"
J. Phys. Chem. C, 2014, 118, 20504?20510.
・"Surface-Fixation Induced Emission” of Porphyrazine Dye by a Complexation with Inorganic Nanosheets"
J. Phys. Chem. C, 2014, 118, 20466?20471.
・層状化合物(化学の要点シ リーズ 11)」(共立出版)
・Microstructure and the Mobility of Fluorinated Carbon Chain of Reversed Micelles Formed by Cationic Polyfluorinated Surfactant
Bull. Chem. Soc. Jpn. 2014, 87, 1273-1277.
・Supramolecular-Surface Photochemistry: Supramolecular Assembly Organized on a Clay Surface Facilitates Energy Transfer Between an Encapsulated Donor and a Free Acceptor
Ishida, Yohei; Kulasekharan, Revathy; Shimada, Tetsuya; Ramamurthy, Vaidhyanathan; Takagi, Shinsuke
J. Phys. Chem. C, 2014, 118, 10198.
・Preparation of the modified mica for the effective adsorbent to remove Cs+ from water
Chem. Lett. 2014, 43, 860-861.
・"Pinning effect for photoisomerization of dicationic azobenzene derivative by anionic sites of clay surface"
Chem. Commun., 2014, 50, 314-316.
・特願2013-172953 :表面電荷を有する無機ナノシートとの複合化による多価イオン性分子の異性化反応の制御 (異性化反応制御方法、および異性体製造方法)
・“次世代型”超分子系人工光捕集システムの開発(総説、依頼執筆)
高木慎介、嶋田哲也
光化学協会誌, 2013, 44, 138-145.
・Photochemical Properties of Mono-, Tri-, Penta- Cationic Antimony(V) Metalloporphyrin Derivatives on Clay Layer Surface
J. Phys. Chem. A 2013, 117, 7823-7832.
・分子光化学の原理(丸善出版)、2013 (部分担当)
・粘土ナノシート/有機色素複合体の光化学特性とその応用(総説、依頼執筆)
塚本孝政、嶋田哲也、高木慎介
無機マテリアル学会誌、J. Soc. Inorg. Mater, Jpn., 2014, 21, 54-60.
・粘土ナノシートにより形成される機能性色素材料(総説、依頼執筆)
塚本孝政、嶋田哲也、高木慎介
色材協会誌、J. Jpn. Soc. Colour Mater., 2013, 86, 198-203.
・Oxygen sensing materials based on clay/metalloporphyrin hybrid systems"
Cent. Eur. J. Chem. 11(7) ? 2013 ? 1132-1136.
(スロバキア科学アカデミー Alexander ?eklovsky?先生との共同研究によるものです)
・Artificial Light-Harvesting Model in a Self-Assembly Composed of Cationic Dyes and Inorganic Nanosheet
J. Phys. Chem. C, 2013, 117, 9154?9163.
・The Role of Hydrophobic Interaction in Controlling the Orientation of Dicationic Porphyrins on Solid Surfaces
J. Phys. Chem. C, 2013, 117, 9245?9251.
(筑波大学 江口美陽先生、山梨大学 D. A. Tryk先生との共同研究によるものです)
・High Density Intercalation of Porphyrin into Transparent Clay Membrane without Aggregation
Langmuir, 2013, 29, 5060?5065.
(島根大学 笹井亮准教授との共同研究によるものです)
・The adsorption behavior of protonated cationic porphyrin on the clay surface
Clay Science, 2013, 17, 31-34.
(筑波大学 江口美陽先生との共同研究によるものです)
・Efficient Singlet-Singlet Energy Transfer in a Novel Host-Guest Assembly Composed of an Organic Cavitand, Aromatic Molecules and Clay Nano-sheet
Yohei Ishida, Revathy Kulasekharan, Tetsuya Shimada, Shinsuke Takagi*, V. Ramamurthy*
Langmuir, 2013, 29, 1748?1753.(米国マイアミ大学 V. Ramamurthy教授との共同研究によるものです)
・Unique Photochemical Properties of p-Substituted Cationic Triphenylbenzene Derivatives on Clay Layer Surface
J. Phys. Chem. C, 2013, 117, 2774?2779.
・Size-matching effect on inorganic nano-sheets: Control of distance, alignment, orientation of molecular adsorption as a bottom-up methodology for nano-materials
Langmuir (Invited Feature Article), 2013, 29, 2108?2119.
・特願2013-56199 :放射性イオンの抽出方法、及び放射性イオン抽出システム
Yohei Ishida, Shinsuke Takagi
Editor(s):Youhong Tang, Ben Zhong Tang
2022 John Wiley & Sons Ltd.
"Photo-cyclization, Photo-ring opening and Thermo-ring opening Reaction of Cationic Diarylethene Adsorbed on the Clay Nanosheet Surface"
Kyosuke Arakawa, Tetsuya Shimada, Tamao Ishida, ShinsukeTakagi
Colloids and Surfaces A: Physicochemical and Engineering Aspects, Available online 11 November 2022, 130537
"Enhancement effect of strong metal-support interaction (SMSI) on the catalytic activity of substituted-hydroxyapatite supported Au clusters"
Akihiro Nakayama, Ryusei Sodenaga, Yuvaraj Gangarajula, Ayako Taketoshi, Toru Murayama, Tetsuo Honma, Norihito Sakaguchi, Tetsuya Shimada, Shinsuke Takagi, Masatake Haruta, Botao Qiao, Junhu Wang,Tamao Ishida
Journal of Catalysis Volume 410, June 2022, Pages 194-205.
"Photochemical hydrogen evolution using Pt/titania nanosheet catalysts prepared by chemical-reduction and photo-deposition methods"
Hosei Takimoto, Yugo Hirade, Tetsuya Shimada, Tamao Ishida and Shinsuke Takagi
Results in Chemistry 2022, 4, 100271. https://doi.org/10.1016/j.rechem.2021.100271
"Precise evaluation of adsorption behavior of cationic porphyrin on monolayer of perovskite-type niobia nanosheet by absorption spectroscopy"
Momoka Oshima, Keito Sano, Yugo Hirade, Ryosuke Nakazato, Tamao Ishida, Tetsuya Shimada, Shinsuke Takagi
Journal of Physics and Chemistry of Solids 2022, 161, 110423. https://doi.org/10.1016/j.jpcs.2021.110423
・光化学協会「光化学」
プリフィス"カーボンニュートラルと光化学"
光化学, 2021, 52, 45.
・日本化学会「低次元系光機 能材料研究会 ニュースレター」
"なぜ化学を研究するのか"
低次元系光機能材料研究会ニュースレター, 2021, 24, 7-13.
・"Estimation of adsorption distribution of di-cationic porphyrin on anionic nanosheet surface using self-fluorescence quenching as a probe"
Yutaka Ohsaki, Ryohei Shibatani, Tetsuya Shimada, Tamao Ishida, Shinsuke Takagi
Chem. Lett. 2021, in press.
・"Effects of Surface Charge Density of Clay Minerals on Surface-fixation Induced Emission (S-FIE) of Acridinium Derivatives"
Shinsuke Takagi,* et. al.
ACS Omega 2021, 6, 33, 21702–21708. Link
・"“In-water” Dehydration reaction of Aromatic Diol on Inorganic Surface"
Shinsuke Takagi,* et. al.
Langmuir 2021, 37, 11978–11985. Link
・"Acid-base equilibria of axial ligand and peripheral pyridyl group with stepwise formation of nine species of aluminum (III) tera (4-pyridyl) porphyrin"
Siby Mathew, AbinSebastian, Fazalurahman Kuttassery, Shinsuke Takagi, Hiroshi Tachibana, Haruo Inoue
Inorganica Chimica Acta, 2021, 526, 120529.
・"UNIQUE NON SELF-LUMINESCENCE QUENCHING BEHAVIOR OF CATIONIC Pt(IV)PORPHYRIN ON CLAY SURFACE"
Shinsuke Takagi,* et. al.
Clay Science, in press.
・"Adsorption and absorption behavior of cationic porphyrin on titania and clay nanosheets"
Shinsuke Takagi,* et. al.
Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2021, 624, 126747.
・"Dye-sensitized Hydrogen Production by Porphyrin/Rh-doped-Titania-Nanosheet Complex"
Shinsuke Takagi,* et. al.
Bulletin of the Chemical Society of Japan, 2021, 94, 937-942.
・"Effect of Li ions Doping into p-type Semiconductor NiO as a Hole Injection/Transfer Medium in the CO2 Reduction Sensitized/Catalyzed by Zn-porphyrin/Re-complex upon Visible Light Irradiation"
Shinsuke Takagi,* et. al.
Res. Chem. Intermed., 2021, 47, 269-285.
・"Adsorption Orientation Control of Di-cationic Porphyrin on Titania-nanosheet"
Tetrahedron Letters, 2020, 61, 152494.
・"Optically Transparent Colloidal Dispersion of TiO2 Nanoparticles Storable for longer than One year Prepared by Sol/Gel Progressive Hydrolysis/Condensation"
ACS Applied Material and Interface, 2020, 12, 44743-44753.
・Dyes and Photoactive Molecules in Microporous Systems、 2020 Springer Natureが発刊されました。
Tuning emission properties by dye encapsulation into layered silicates を執筆しています。
・ "Two-electron oxidation of water to form hydrogen peroxide initiated by one-electron oxidation of Tin (IV)-porphyrins"
Journal of Photochemistry & Photobiology, A: Chemistry, 2020, 401, 112732.
・"Anisotropic energy transfer in the clay-porphyrin layered system with environment-responsiveness"
Physical Chemistry Chemical Physics, 2020, 22, 14261-14267.
・ "Adsorption Behavior of Mono-cationic Acridinium Derivatives on Clay Surface"
RSC Advances, 2020, 10, 21360 - 21368
・"Unique enzyme activity of peroxidase on the clay-nanosheet"
Langmuir 2020, 36, 29, 8384–8388
・(島根大学 藤村卓也先生との共同研究によるものです)
"Adsorption behavior of mono-cationic pyridinium salts on the clay surface"
doi:10.1246/bcsj.20200100
・(島根大学 藤村卓也先生、笹井亮先生との共同研究によるものです)
"Photoreduction of Methylviologen in Saponite Clay: Effect of Methylviologen Adsorption Density on the Reaction Efficiency"
https://doi.org/10.1007/s42860-019-00047-8
・特集/ナノテクノロジーの新展開・ナノシートとの複合化による強発光性材料の開発, S. Takagi, K. Arakawa, 化学工業誌, 2020, 71, 14-18.
・"Effect of clay surface on aldehyde-diol equilibrium"
Tetrahedron Letters, 2019, 60, 150986. DOI: 10.1016/j.tetlet.2019.150986
・ "Factors for the emission enhancement of dimidium in the specific medium such as DNA and clay surface"
Physical Chemistry Chemical Physics, 2019, 21, 22732 - 22739. DOI: 10.1039/C9CP03285A
Selected as inside cover article
・Reversed Micelles Formed by Polyfluorinated Surfactant II; the Properties of Core Water Phase in Reversed Micelle
Bulletin of the Chemical Society of Japan, doi:10.1246/bcsj.20190086
・ "Which Type of Clay Minerals Fix Cesium Ion Effectively? -Cavity-Charge Matching Effect- "
Physical Chemistry Chemical Physics, 2019, 21, 9352 - 9356. DOI: 10.1039/C9CP00457B
・"An Artificial Photosynthesis Model: Photochemical Reaction System with Efficient Light Harvesting Function on Inorganic Nanosheets"
Shinsuke Takagi,* et. al.
ACS Omega, 2018, 3 (12), pp 18563–18571
・Sebastian Nybin Remello, Fazalurahman Kuttassery, Siby Mathew, Arun Thomas, Daisuke Yamamoto, Yu Nabetani, Keito Sano, Hiroshi Tachibana and Haruo Inoue *
"Two-electron oxidation of water to form hydrogen peroxide catalysed by silicon-porphyrins"
Sustainable Energy Fuels, 2018, 2, 1966–1973.
・"How does the tin(IV)-insertion to porphyrins proceed in water at ambient temperature?: Re-investigation by time dependent 1H NMR and detection of intermediates"
Inorganica Chimica Acta 482 (2018) 914–924.
・"Adsorption and Emission Enhancement Behavior of 4,4-Bipyridine on Dispersed Montmorillonite Nano-sheets under Aqueous Conditions"
Shinsuke Takagi,* et. al.
・以下の論文がオンラインニュースサイトEurekAlert!に掲載されました!
Langmuir, 2018, 34 (12), pp 3572–3577.
・Chem. Lett.誌
" Efficient Electron Injection from Excited Porphyrin to Titania Nanosheet"
Shinsuke Takagi,* et. al.
・島根大学 藤村卓也先生、笹井亮先生との共同研究によるものです)
"Optical Humidity Sensing Using Transparent Hybrid Film Composed of Cationic Magnesium Porphyrin and Clay Mineral"
Shinsuke Takagi,* et. al.
・J. Phys. Chem. C
"Elucidation of the Adsorption Distribution of Cationic Porphyrin on the Inorganic Surface by Energy Transfer as a Molecular Ruler"
Shinsuke Takagi,* et. al.
・Langmuir誌(信州大学 岡田友彦先生との共同研究によるものです)
"Photoluminescence by Intercalation of a Fluorescent β?Diketone Dye into a Layered Silicate"
Langmuir, 2017, 33, 13515?13521.
・2017年8月 特許 第6183838号 異性化反応制御方法、及び異性体製造方法
・"Characterization of Dispersed Titania Nanosheet under Aqueous Conditions and its Complex Formation Behavior with Cationic Porphyrin"
Shinsuke Takagi,* et. al.
J. Photochem. Photobiol. A, 2017, 353, 597-601.
・"Highly Selective Photochemical Epoxidation of Cyclohexene Sensitized by Ru(II) Porphyrin-Clay Hybrid Catalyst"
Chem. Lett., 2017, 30, 128-129.
・2017年5月 Springer社 Inorganic Nanosheets and Nanosheet-Based Materials (Fundamentals and Applications of Two-Dimensional Systems, Editors: Nakato, Teruyuki, Kawamata, Jun, Takagi, Shinsuke (Eds.))
・2017年5月 化学と工業5月号の特集(相乗効果を産み出す層状構造)"層状無機化合物と光化学"(高木慎介
・2017年3月 日本化学会[CSJカレントレビュー25]二次元物質の科学 グラフェンなどの分子シートが生み出す新世界
・Langmuir誌
(新潟大学 由井樹人先生との共同研究によるものです)
"Light Energy Accumulation from Pyrene Derivative to Tris(bipyridine)ruthenium on Clay Surface"
Langmuir, 2017, 33, 3680-3684.
・Journal of Photochemistry and Photobiology A: Chemistry
(新潟大学 由井樹人先生との共同研究によるものです)
"Color Tuning of Cationic Pyrene Derivatives on Clay Nano-sheet: Retardation of Gradual Red Shift on Clay"
J. Photochem. Photobiol. A: Chem. 2017, 337, 112?117.
・Royal Society of Chemistry Physical Chemistry Chemical Physics 誌
(島根大学 笹井亮先生との共同研究によるものです)
"Photoinduced electron transfer in layer-by-layer thin solid films containing cobalt oxide nanosheets, porphyrin, and methylviologen"
R. Sasai, Y. Kato, W. Soontornchaiyakul, H. Usami, A. Masumori, W. Norimatsu, T. Fujimura, S. Takagi
Physical Chemistry Chemical Physics 2017, 19, 5611-5616.
・"Size-Matching Effect” in Cationic Porphyrin-Titania Nanosheet Complex"
Sonotani, Amane; Shimada, Tetsuya; Takagi, Shinsuke
Chemistry Letters 2017, 46, 499-501.
・Journal of Photochemistry and Photobiology A: Chemistry誌
(新潟大学 由井樹人先生との共同研究によるものです)
"Color Tuning of Cationic Pyrene Derivatives on Clay Nano-sheet: Retardation of Gradual Red Shift on Clay"
J. Photochem. Photobiol. A: Chem. 2017, in press.
・Physical Chemistry Chemical Physics 誌 (IF = 4.493)
"Photoinduced electron transfer in layer-by-layer thin solid films containing cobalt oxide nanosheets, porphyrin, and methylviologen"
R. Sasai, Y. Kato, W. Soontornchaiyakul, H. Usami, A. Masumori, W. Norimatsu, T. Fujimura, S. Takagi
Physical Chemistry Chemical Physics 2017, in press.
・"Size-Matching Effect” in Cationic Porphyrin-Titania Nanosheet Complex"
Shinsuke Takagi,* et. al.
Chemistry Letters 2017, 46, 499-501.
・Journal of Photochemistry and Photobiology A: Chemistry誌(Invited Feature Article)
"Unique Fluorescence Behavior of Dyes on the Clay Minerals Surface: Surface Fixation Induced Emission (S-FIE)"
Shinsuke Takagi,* et. al.
J. Photochem. Photobiol. A: Chem. 2017, 339, 67-79.
・"Energy Transfer among Three Dye Components in a Nanosheet?Dye Complex: An Approach to Evaluating the Performance of a Light-Harvesting System"
Shinsuke Takagi,* et. al.
J. Phys. Chem. C, 2017, in press.
・"Room Temperature Phosphorescence from a Guest Molecule Confined in Restrictive Space of an Organic?Inorganic Supramolecular Assembly"
Yohei Ishida, Tetsuya Shimada, Elamparuthi Ramasamy, Vaidhyanathan Ramamurthy* and Shinsuke Takagi*
Photochemical & Photobiological Sciences, 2016, 15, 959-963.
・"Supramolecular-Surface Photochemistry: Cascade Energy Transfer between Encapsulated Dyes Aligned on Clay Nano-sheet Surface"
Tsukamoto, Takamasa; Ramasamy , Elamparuthi ; Shimada, Tetsuya; Takagi, Shinsuke; Ramamurthy, Vaidhyanathan
Langmuir, 2016, 32, 2920.
・"Kinetic Analysis by Laser Flash Photolysis of Porphyrin Molecules’ Orientation Change at the Surface of Silicate Nanosheet"
Shinsuke Takagi,* et. al.
J, Phys. Chem. C, 2016, 120, 7428?7434
・"Photophysical Properties and Adsorption Behaviors of Novel Tri-Cationic Boron(III) Subporphyrin on Anionic Clay Surface"
Shinsuke Takagi,* et. al.
ACS Applied Materials & Interfaces, 2016, 8, 7522-7528.
・"Supramolecular-Surface Photochemistry: Sequential Energy and Electron Transfer in a Three-component System Aligned on a Clay Nanosheet"
Takuya Fujimura, Elamparuthi Ramasamy, Yohei Ishida, Tetsuya Shimada, Shinsuke Takagi*, Vaidhyanathan Ramamurthy*
Physical Chemistry Chemical Physics, 2016,18, 5404-5411.
(米国Miami大学 V. Ramamurthy先生、島根大学 藤村卓也先生との共同研究によるものです)
・"Emission amplification of Ru(bpy)32+ via energy transfer from pyrene derivatives on synthesized clay"
Journal of Photochemistry and Photobiology A: Chemistry 313 (2015) 9?14.
・"Dense Deposition of Gold Nano Clusters Utilizing a Porphyrin/Inorganic Layered Material Complex as the Template"
Shinsuke Takagi,* et. al.
Langmuir, 2015, 31, 9142?9147
・"The Artificial Light Harvesting System with Energy Migration Functionality in the Cationic Dyes / Inorganic Nano-sheet Complex"
Shinsuke Takagi,* et. al.
J. Phys. Chem. C, 2015, 119 (33), pp 18896?18902
・"Anisotropic Photochemical Energy Transfer in Clay / Porphyrin System Prepared by Size-matching effect and Langmuir-Blodgett Technique"
Shinsuke Takagi,* et. al.
Journal of Photochemistry and Photobiology A: Chemistry 2015, 313, 15?18.
・"Remarkable stimulation of emission quenching on a clay surface"
Sato, K., Matsubara, K., Hagiwara, S., Saito, K., Yagi, M., Takagi, S., Yui, T.
Langmuir 2015, 31, 27-31.
・"Photochemical Chlorination and Oxygenation Reaction of Cyclohexene Sensitized by Ga(III) Porphyrin-Clay Minerals System with High Durability and Usability"
T. Tsukamoto, T. Shimada, T. Shiragami, S. Takagi
Bulletin of the Chemical Society of Japan, 2015, 88, 578-583.
・"Structure resembling effect of clay surface on photochemical properties of meso-phenyl or pyridyl-substituted monocationic antimony(V) porphyrin derivatives"
RSC Advances, 2015, 5, 8479-8485.
・「光合成研究と産業応用最前線」(エヌ・ティー・エス) 部分執筆
・"Microstructures of Porphyrin/Viologen Monolayer on the Clay Surface: Segregation or Integration?"
J. Phys. Chem. C, 2014, 118, 20504?20510.
・"Surface-Fixation Induced Emission” of Porphyrazine Dye by a Complexation with Inorganic Nanosheets"
J. Phys. Chem. C, 2014, 118, 20466?20471.
・層状化合物(化学の要点シ リーズ 11)」(共立出版)
・Microstructure and the Mobility of Fluorinated Carbon Chain of Reversed Micelles Formed by Cationic Polyfluorinated Surfactant
Bull. Chem. Soc. Jpn. 2014, 87, 1273-1277.
・Supramolecular-Surface Photochemistry: Supramolecular Assembly Organized on a Clay Surface Facilitates Energy Transfer Between an Encapsulated Donor and a Free Acceptor
Ishida, Yohei; Kulasekharan, Revathy; Shimada, Tetsuya; Ramamurthy, Vaidhyanathan; Takagi, Shinsuke
J. Phys. Chem. C, 2014, 118, 10198.
・Preparation of the modified mica for the effective adsorbent to remove Cs+ from water
Chem. Lett. 2014, 43, 860-861.
・"Pinning effect for photoisomerization of dicationic azobenzene derivative by anionic sites of clay surface"
Chem. Commun., 2014, 50, 314-316.
・特願2013-172953 :表面電荷を有する無機ナノシートとの複合化による多価イオン性分子の異性化反応の制御 (異性化反応制御方法、および異性体製造方法)
・“次世代型”超分子系人工光捕集システムの開発(総説、依頼執筆)
高木慎介、嶋田哲也
光化学協会誌, 2013, 44, 138-145.
・Photochemical Properties of Mono-, Tri-, Penta- Cationic Antimony(V) Metalloporphyrin Derivatives on Clay Layer Surface
J. Phys. Chem. A 2013, 117, 7823-7832.
・分子光化学の原理(丸善出版)、2013 (部分担当)
・粘土ナノシート/有機色素複合体の光化学特性とその応用(総説、依頼執筆)
塚本孝政、嶋田哲也、高木慎介
無機マテリアル学会誌、J. Soc. Inorg. Mater, Jpn., 2014, 21, 54-60.
・粘土ナノシートにより形成される機能性色素材料(総説、依頼執筆)
塚本孝政、嶋田哲也、高木慎介
色材協会誌、J. Jpn. Soc. Colour Mater., 2013, 86, 198-203.
・Oxygen sensing materials based on clay/metalloporphyrin hybrid systems"
Cent. Eur. J. Chem. 11(7) ? 2013 ? 1132-1136.
(スロバキア科学アカデミー Alexander ?eklovsky?先生との共同研究によるものです)
・Artificial Light-Harvesting Model in a Self-Assembly Composed of Cationic Dyes and Inorganic Nanosheet
J. Phys. Chem. C, 2013, 117, 9154?9163.
・The Role of Hydrophobic Interaction in Controlling the Orientation of Dicationic Porphyrins on Solid Surfaces
J. Phys. Chem. C, 2013, 117, 9245?9251.
(筑波大学 江口美陽先生、山梨大学 D. A. Tryk先生との共同研究によるものです)
・High Density Intercalation of Porphyrin into Transparent Clay Membrane without Aggregation
Langmuir, 2013, 29, 5060?5065.
(島根大学 笹井亮准教授との共同研究によるものです)
・The adsorption behavior of protonated cationic porphyrin on the clay surface
Clay Science, 2013, 17, 31-34.
(筑波大学 江口美陽先生との共同研究によるものです)
・Efficient Singlet-Singlet Energy Transfer in a Novel Host-Guest Assembly Composed of an Organic Cavitand, Aromatic Molecules and Clay Nano-sheet
Yohei Ishida, Revathy Kulasekharan, Tetsuya Shimada, Shinsuke Takagi*, V. Ramamurthy*
Langmuir, 2013, 29, 1748?1753.(米国マイアミ大学 V. Ramamurthy教授との共同研究によるものです)
・Unique Photochemical Properties of p-Substituted Cationic Triphenylbenzene Derivatives on Clay Layer Surface
J. Phys. Chem. C, 2013, 117, 2774?2779.
・Size-matching effect on inorganic nano-sheets: Control of distance, alignment, orientation of molecular adsorption as a bottom-up methodology for nano-materials
Langmuir (Invited Feature Article), 2013, 29, 2108?2119.
・特願2013-56199 :放射性イオンの抽出方法、及び放射性イオン抽出システム
・2018 日本粘土学会賞
・2015 光化学協会賞
・2013 積水化学「自然に学ぶものづくり研究 助成プログラム」奨励賞
・2011 the Tokyo u-club「都市に関する研究奨励賞」優秀賞
受賞タイトル「太陽光の有効利用を目指した、人工光捕集システムの構築」
・2009 感謝状 Top 20% of reviewers for Langmuir
・2009 日本粘土学会奨励賞
「粘土鉱物ーポルフィリン複合体における“Size-MatchingEffect”の発見と、その光化学反応への応用」
高木慎介
9月11日 粘土科学討論会、岩手大学にて
・2005 化学のフロンティア2005ーはばたけ若き研究者たちー
「層状化合物-ポルフィリン複合体における分子配列と分子配向制御ー思いどおりに分子を並べたい」
高木慎介
化学と工業(日本化学会)、2005、Vol.58-2、121-124.
・2004 APA Prize for Young Scientist(Jan. 08, 2005台湾台北市圓山大飯店にて)
APA(The Asian and Oceanian Photochemistry Association)
"The nano-structure control of complexes composed of porphyrin and layered materials, and their applications to photochemical reactions."
Shinsuke TAKAGI
・2015 光化学協会賞
・2013 積水化学「自然に学ぶものづくり研究 助成プログラム」奨励賞
・2011 the Tokyo u-club「都市に関する研究奨励賞」優秀賞
受賞タイトル「太陽光の有効利用を目指した、人工光捕集システムの構築」
・2009 感謝状 Top 20% of reviewers for Langmuir
・2009 日本粘土学会奨励賞
「粘土鉱物ーポルフィリン複合体における“Size-MatchingEffect”の発見と、その光化学反応への応用」
高木慎介
9月11日 粘土科学討論会、岩手大学にて
・2005 化学のフロンティア2005ーはばたけ若き研究者たちー
「層状化合物-ポルフィリン複合体における分子配列と分子配向制御ー思いどおりに分子を並べたい」
高木慎介
化学と工業(日本化学会)、2005、Vol.58-2、121-124.
・2004 APA Prize for Young Scientist(Jan. 08, 2005台湾台北市圓山大飯店にて)
APA(The Asian and Oceanian Photochemistry Association)
"The nano-structure control of complexes composed of porphyrin and layered materials, and their applications to photochemical reactions."
Shinsuke TAKAGI
光化学協会(常任理事、事務局長)、アジアオセアニア光化学協会(理事、事務局長)
日本化学会研究会「低次元系光機能材料研究会」(運営委員)
2016,2017コース長,学域長、2016主幹教授
大阪府立大学 客員教授
光化学協会(常任理事)
アジアオセアニア光化学協会(理事)
日本化学会(光化学ディビジョン幹事)
日本粘土学会(理事)
日本化学会研究会「低次元系光機能材料研究会」(顧問)
カーボン・エネルギーコントロール社会協議会 (CanApple): フォーラム人工光合成ネットワーク副代表
固体・表面光化学討論会 共同代表
日本粘土学会 Clay Science誌 Editor (2012-)
Elsevier J.Photochem. Photobiol. C (IF=16.091) Associate Editor (2016-)
Elsevier J.Photochem. Photobiol. Editorial Board (2021-)
光化学協会誌編集委員 (2016-)
アメリカ化学会 Langmuir誌 Editorial Advisory Board (2013-2016)
日本化学会研究会「低次元系光機能材料研究会」(運営委員)
2016,2017コース長,学域長、2016主幹教授
大阪府立大学 客員教授
光化学協会(常任理事)
アジアオセアニア光化学協会(理事)
日本化学会(光化学ディビジョン幹事)
日本粘土学会(理事)
日本化学会研究会「低次元系光機能材料研究会」(顧問)
カーボン・エネルギーコントロール社会協議会 (CanApple): フォーラム人工光合成ネットワーク副代表
固体・表面光化学討論会 共同代表
日本粘土学会 Clay Science誌 Editor (2012-)
Elsevier J.Photochem. Photobiol. C (IF=16.091) Associate Editor (2016-)
Elsevier J.Photochem. Photobiol. Editorial Board (2021-)
光化学協会誌編集委員 (2016-)
アメリカ化学会 Langmuir誌 Editorial Advisory Board (2013-2016)
下記の活動などを通じて、エネルギー問題、環境問題の解決に向け研究を進めている。
夢ナビ講師(2回)
科学技術戦略推進費「天然鉱物等の無機材料を利用した環境からの放射性物質回収・除去技術等の 開発」プロジェクトへの参加
新学術領域研究「人工光合成による太陽光エネルギーの物質変換: 実用化に向けての異分野融合」 に公募研究者として参加
積水化学「自然に学ぶものづくり研究 助成プログラム」
複数の企業との共同研究など
カーボン・エネルギーコントロール社会協議会 (CanApple): フォーラム人工光合成ネットワーク副代表
また、Clay Science誌のEditor in Chief、アメリカ化学会 Langmuir誌 Advisory Editorial Board、日本化学会研究会役員、カーボン・エネルギーコントロール社会協議会 (CanApple): フォーラム人工光合成ネットワーク副代表をつとめるなどの学会活動を行っている。
夢ナビ講師(2回)
科学技術戦略推進費「天然鉱物等の無機材料を利用した環境からの放射性物質回収・除去技術等の 開発」プロジェクトへの参加
新学術領域研究「人工光合成による太陽光エネルギーの物質変換: 実用化に向けての異分野融合」 に公募研究者として参加
積水化学「自然に学ぶものづくり研究 助成プログラム」
複数の企業との共同研究など
カーボン・エネルギーコントロール社会協議会 (CanApple): フォーラム人工光合成ネットワーク副代表
また、Clay Science誌のEditor in Chief、アメリカ化学会 Langmuir誌 Advisory Editorial Board、日本化学会研究会役員、カーボン・エネルギーコントロール社会協議会 (CanApple): フォーラム人工光合成ネットワーク副代表をつとめるなどの学会活動を行っている。
- 物質量子化学
- 物理有機化学
- 物質量子化学
- 物理有機化学
- 環境分子化学講究Ⅰ
- 環境分子化学講究Ⅱ
- Advanced Physical Chemistry
- エネルギー化学入門
- 組織再編前旧課程の同時開講科目等が含まれており、掲載されている全ての科目を開講するわけではありません。
関連HOT TOPICS
すべて見る連絡先
研究室
9号館446号室
オフィスアワー
月 15:00-17:00 及び、各講義の終了直後
内線番号
内線4893
メールアドレス
takagi-shinsuke●tmu.ac.jp
(メールを送信される場合は●を@に変換してください)