SUGIURA Ken-ichi

杉浦 健一 スギウラ ケンイチ すぎうら けんいち



東京都立大学理学部 化学科
理学研究科 化学専攻


■ 1992年9月:総合研究大学院大学・数物科学研究科・機能分子科学専攻・博士後期課程・修了
■ 1989年3月:大阪大学大学院・理学研究科・有機化学専攻・博士前期課程・修了
■ 1989年3月:北海道大学・理学部・化学第二学科・卒業


■ 合成化学



■ ポルフィリンを用いた多段階酸化還元配位子の合成と性質の評価
■ 拡張π電子系を有した新しい不斉配位子と金属錯体の合成と分光学的挙動


■ 錯体化学
■ 有機合成化学
■ ナノテクノロジー
■ 巨大分子
■ 不斉化学



■ "Unexpected phenyl group rearrangement of Thiele’s hydrocarbon derivative under polycyclic aromatic hydrocarbon synthesis", Firyon Ko, Kazunori Hirabayashi, Toshio Shimizu, and Ken-ichi Sugiura, Tetrahedron Letters, 59, in press, 2018.

■ "Versatile and Catalyst‐Free Methods for the Introduction of Group‐16 Elements at the meso‐Positions of Diarylporphyrins", Ken‐ichi Yamashita, Kazuyuki Kataoka, Hang Pham?Qui?Van, Takuji Ogawa, and Ken‐ichi Sugiura, Asian Journal of Organic Chemistry, 7, in press, 2018.
(DOI: 10.1002/ajoc.201800538)

■ "Synthesis, Optical Resolution, and Circularly Polarized Luminescence of an Axially
Chiral Porphyrin Dimer", Risa Watanabe, Nobuyuki Hara, Yoshitane Imai, Masashi Hasegawa, Sumire Ishioka, Yasuhiro Mazaki, and Ken-ichi Sugiura, Chmemistry Select, 3, 3576-3581, 2018.
(DOI: 10.1002/slct.201800213)
(Front Cover Picture)

■ "Syntheses, structural characterization, and basic properties of unsymmetrically substituted biphenoquinones", Ryotaro Fujii and Ken-ichi Sugiura, Journal of Molecular Structure, 1156, 559-563, 2018.
(DOI: 10.1016/j.molstruc.2017.12.006)

■ "Synthesis of Tetra(3-thienyl)biphenoquinone and Its Charge Transfer Complex with Perylene", Ryotaro Fujii, Md. Awlad Hossain, Hisato Akimoto, Kazunori Hirabayashi, Toshio Shimizu, Kazuhiko Akiyama, Kenta Goto, Hiroyuki Nishikawa, Ken-ichi Yamashita, and Ken-ichi Sugiura, Asian Journal of Organic Chemistry, 7(1), 171-178, 2018.
(DOI: 10.1002/ajoc.201700560)


■ "An Alternative Synthesis of Bipyrenol: High-Yield Oxidative Coupling Reaction of Pyrene Derivative with Cu(BF4)2・nH2O", Subas Rajbangshi and Ken-ichi Sugiura,* Synthesis, 49(14), 3145-3148, 2017.
(DOI: 10.1055/s-0036-1588819)

■ "Thiophene-Fused Dinaphthopentaphenes: Versatile Applications of 1,2-Bis(pyren-2-yl)aromatics in the Synthesis of pai-Expanded Molecules", Md. Awlad Hossain, Ken-ichi Yamashita, Kazunori Hirabayashi, Toshio Shimizu, Kenta Goto, and Ken-ichi Sugiura,* Chemistry Select, 2(16), 4342-4347, 2017.
(DOI: 10.1002/slct.201700152)

■ "meso-Bis(pyren-2-yl)porphyrin: An Isomer of Pyrene-Substituted Porphyrins and its Basic Photophysical Properties", Shohei Tomita, Kazunori Hirabayashi, Toshio Shimizu, Kenta Goto, and Ken-ichi Sugiura,* Synthesis, 49(10), 2182-2186, 2017.
(DOI: 10.1055/s-0036-1588715)

■ Md. Awlad Hossain, Kazuhiko Akiyama, and Ken-ichi Sugiura,* "Pyren-2-yl-substituted Biphenoquinone and p-Benzoquinone: Pyren-2-yl as a Weak Electron-Withdrawing Substituent" Chemistry Select, 1(21) (2016) 6859-6865.
(DOI: 10.1002/slct.201601371)

■ Ken-ichi Yamashita,* Kazuyuki Kataoka, Shouichi Takeuchi, Ken-ichi Sugiura,* "Metal-Free Synthesis of meso-Aminoporphyrins through Reduction of meso-Azidoporphyrins Generated In Situ by Nucleophilic Substitution Reactions of meso-Bromoporphyrins" Journal of Organic Chemistry, 81(22) (2016) 11176-11184.
(DOI: 10.1021/acs.joc.6b02159)

■ Md. Awlad Hossain, Kazuhiko Akiyama, and Ken-ichi Sugiura,* "Synthesis of 3,3'',5,5''-tetraphenyl-4,4''-terphenoquinone and its reductive disproportionation reaction" Chemistry Select, 1(13) (2016) 4137-4142.
(DOI: 10.1002/slct.201600958)

■ Md. Awlad Hossain, Kazuhiko Akiyama, Kenta Goto, and Ken-ichi Sugiura,* "Thermal reductive disproportionation of 3,3',5,5'-tetraphenyldiphenoquinone with drastic color change: Potential prototype of data storage advanced materials" Chemistry Select, 1(13) (2016) 3784-3790.
(DOI: 10.1002/slct.201600437)

■ Shahed Rana, Ken-ichi Yamashita, and Ken-ichi Sugiura,* "Oligomerization of Bis(ethynyl)tetraphenylporphyrin Derivatives by Glaser-Hay Coupling Reaction: Isolation and Characterization of Dimer, Trimer, and Tetramer" Synthesis, 48(15) (2016) 2461-2465.
(DOI: 10.1055/s-0035-1560447)

■ Ken-ichi Yamashita, Shino Sakamoto, Akihiro Suzuki, and Ken-ichi Sugiura,* "Molecular Design and Syntheses of Tetracyano-5,10-porphyrinquinodimethane Showing Stabilized LUMO" Chemistry-An Asian Journal, 11(7) (2016) 1004-1007.
(DOI: 10.1002/asia.201600147)

■ Ken-ichi Yamashita, Shin Tazawa, Ken-ichi Sugiura,* "Oxo(porphyrinato)vanadium(IV) as a standard for geoporphyrins" Inorganica Chimica Acta, 439(1) (2016) 173-177.
(DOI: 10.1016/j.ica.2015.10.019)

■ Luong Xuan Dien, Ken-ichi Yamashita, Ken-ichi Sugiura,* "Metal complexes of pai-expanded ligands (2): Synthesis and characterizations of bis[2-[(octylimino)methyl]-1-pyrenolato-N,O]palladium(II) and the stabilized vacant dx2-y2 orbital" Polyhedron, 102 (2015) 69-74.

■ Luong Xuan Dien, Ken-ichi Yamashita, Motoko S. Asano, Ken-ichi Sugiura,* "Syntheses of a pyrene-based pai-expanded ligand and the corresponding platinum(II) complex, bis[2-[(octylimino)methyl]-1-pyrenolato-N,O]platinum(II)" Inorganica Chimica Acta, 432 (2015) 103-108.

■ Kamrul Hassan, Ken-ichi Yamashita, Kazunori Hirabayashi, Toshio Shimizu, Kazuki Nakabayashi, Yoshitane Imai,* Takashi Matsumoto, Akihito Yamano, and Ken-ichi Sugiura* "π-Expanded Axially Chiral Biaryls and Their Emissions: Molecular Design, Syntheses, Optical Resolution, Absolute Configuration, and Circularly Polarized Luminescence of 1,1'-Bipyrene-2,2'-diols" Chemistry Letters, 44 (2015) 1607-1609. [Editor's Choice]

■ Shahed Rana, Ken-ichi Yamashita, Yasuhiro Akita, and Ken-ichi Sugiura,* "Stepwise Synthesis of Structurally Well-defined Porphyrin Wires Connected by Platinum Acetylides" Chemistry Letters, 44 (2015) 1226-1228.

■ Ken-ichi Yamashita,* Natsuki Katsumata, Shohei Tomita, Miki Fuwa, Keisuke Fujimaki, Takuya Yoda, Daisuke Hirano, and Ken-ichi Sugiura,* "Facile and Practical Synthesis of Platinum(II) Porphyrins under Mild Conditions" Chemistry Letters, 44 (2015) 492-494.

■ Ken-ichi Yamashita, Akihiro Nakamura, and Ken-ichi Sugiura,* "Regioselective Oxidative Oligomerization Reaction of 2-tert-Alkylpyrene and Isolation of Structurally Well-defined 1,3-Pyrenylenes" Chemistry Letters, 44 (2015) 303-305.

■ Ken-ichi Yamashita, Akihiro Nakamura, Md. Awlad Hossain, Kazunori Hirabayashi, Toshio Shimizu, and Ken-ichi Sugiura,* "Oxidative Intramolecular C-C Bond Formation Reaction of 1,2-Bis(pyren-2-yl)benzene: Synthesis and Characterization of Benzodinaphthopentaphene" Bulletin of the Chemical Society of Japan 88 (2015) 1083-1085.

■■ "Oxidation of meso-Diarylporphyrins by a Hypervalent Iodine Compound: Facile Synthesis of meso-Acyloxyporphyrins and Dioxoporphodimethenes", Ken-ichi Yamashita,* Daisuke Hirano, Motoko S. Asano, and Ken-ichi Sugiura,* Chemistry Letters, 43, 1049-1051, 2014.
(DOI: 10.1246/cl.140219)

■ Sugiura, K.-i.; Fujimoto, Y.; Sakata, Y. "A Porphyrin Square: Synthesis of a Square Shaped p-Conjugated Porphyrin Tetramer Connected by Diacetylene Linkages"; Chem. Commun.,, 1105-1106 (2000).

■ Rittenberg, D. K.; Sugiura, K.-i.; Ariff, A. M.; Sakata, Y.; Incarvito, C. D.; Rheingolg, A. L.; Miller, J. S. "Products from the Reaction of meso-tetrakis(4-halophenyl)porphyrinatomanganese(II) and Hexacyanobutadiene (HCBD)"; Chem. Eur. J., 6, 1811-1819 (2000).

■ Sugiura, K.-i.; Mikami, S.; Iwasaki, K.; Hino, S.; Asato, E.; Sakata, Y. "Synthesis, properties, molecular structure and electron transfer salts of 13,13,14,14-tetracyano-1,6- and -1,8-pyrenoquinodimethanes (1,6-TCNP and 1,8-TCNP)"; J. Mater. Chem., 10, 315-320 (2000).

■ Sugiura, K.-i.; Mikami, S.; Johnson, M. T.; Miller, J. S.; Iwasaki, K.; Umishita, K.; Hino, S.; Sakata, Y. "Structure and Magnetic Properties of meso-Tetrakis(2,4,6-trimethylphenyl)porphyrinatomanganese(III) 2,5-Dimethyl-7,7,8,8-tetracyano-p-quinodimethanide with a 2.3 K Tc. The First Example of cis-Coordination of a Tetracyano-p-quinodimethanide"; J. Mater. Chem., 10, 959-964 (2000).

■ Sugiura, K.-i.; Ushiroda, K.; Johnson, M. T.; Miller, J. S.; Sakata, Y. "Ferrimagnetic Ordering of a Methylthio-Substituted Planar Porphyrin Based Electron Transfer Salt, Octakis(2,3,7,8,12,13,17,18-methylthio)porphyrinatomanganese(III) Tetracyanoethanide"; J. Mater. Chem., 10, 2507-2514 (2000).

■ Rittenberg, D. K.; Sugiura, K.-i.; Sakata, Y.; Mikami, S.; Epstein, A. J.; Miller, J. S. "Large Coercivity and High Remanent Magnetization Organic-Based Magents"; Adv. Mater., 12, 126-130 (2000).

■ Furukawa, M.; Tanaka, H.; Sugiura, K.-i.; Sakata, Y.; Kawai, T. "Fabrication of molecular alignment at the specific sites on Cu(111) surface using self-assembly phenomena"; Surf. Sci., 445, L58-L63 (2000).

1994年(平成6年9月)-1995年(6月) 米国ユタ大学招待準教授
■ 日本化学会
■ 有機合成化学協会
■ 基礎有機化学会
■ アメリカ化学会
■ ポルフィリン-フタロシアニン国際学会
  • 化学専門実験I
  • 無機化学総論
  • 無機及分析化学演習
  • 錯体化学
  • 化学学外体験実習
  • 化学セミナー
  • 無機化学各論Ⅲ
  • 化学学外体験実習
  • 化学特論I(無機化学)
  • 化学特別セミナーI
  • 化学特別セミナーII
  • 化学特別セミナーIII
  • 化学特別セミナーIV
  • 化学学外体験実習
  • 化学学外体験実習
  • 化学学外体験実習
  • 化学学外体験実習
  • 化学特別セミナーII
  • 化学特別セミナーI
  • 化学特別セミナーIV
  • 化学特別セミナーIII
  • 組織再編前旧課程の同時開講科目等が含まれており、掲載されている全ての科目を開講するわけではありません。









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