教員イメージ
Hikima Kazuhiro
准教授

引間 和浩 ヒキマ カズヒロ ひきま かずひろ

プロフィール

所属

東京都立大学都市環境学部 環境応用化学科
都市環境科学研究科 環境応用化学域

最終学歴・学位

東京工業大学 物質理工学院 応用化学系 博士後期課程修了(主指導教員:菅野了次教授)・博士(理学)

専門・研究分野

無機材料化学、エネルギー関連化学

研究

研究テーマ

気相・液相・固相合成法により合成したイオン伝導体などの無機材料をLi, Na系を中心とした全固体蓄電デバイスに応用し、電気化学測定法や放射光を含むX線回折・分光法を用いて反応解析を行うことで、エネルギーデバイスに関する基礎研究に取り組んでいます。

研究キーワード

全固体蓄電デバイス、硫化物系固体電解質、液相合成法、気相蒸着法、モデル薄膜、電池反応のその場解析

研究イメージ

詳細情報

原著論文(*:責任著者)
1. 査読付外国語原著論文
[1] Kazuhiro Hikima*, Ikuyo Kusaba, Masaki Shimada, Yuhei Horisawa, Shunsuke Kawaguchi, Minoru Kuzuhara, Hiroyuki Muto, and Atsunori Matsuda*, Rapid Synthesis of Li10GeP2S12-type Li-Si-P-S-Cl Solid Electrolytes via a Solution Method, Electrochemistry, 93, 063013 (2025), DOI: 10.5796/electrochemistry.25-71029.
[2] Kenta Watanabe*, Han-Seul Kim, Kazuhiro Hikima, Naoki Matsui, Kota Suzuki, Hiroyuki Muto, Atsunori Matsuda, Ryoji Kanno, and Masaaki Hirayama*, Self-Closing of Cracks Generated in Microstructure-Controlled 400 μm-Thick Composite Cathodes for All-Solid-State Batteries: Observed by In Situ Scanning Electron Microscopy with Energy-Dispersive X-Ray Spectroscopy, Batteries & Supercaps, 8, e202580601, (2025), DOI: 10.1002/batt.202580601
[3] Kenta Watanabe*, Hideaki Nakayama, Han-Seul Kim, Kazuhiro Hikima, Naoki Matsui, Kota Suzuki, Satoshi Obokata, Hiroyuki Muto, Atsunori Matsuda, Ryoji Kanno, and Masaaki Hirayama*, Sn vs. Ge: Effects of Elastic and Plastic Deformation of LGPS-type Solid Electrolytes on Charge-discharge Properties of Composite Cathodes for All-solid-state Batteries, Electrochemistry, 93, 063019 (2025), DOI: 10.5796/electrochemistry.25-71020.
[4] Reiko Matsuda, Masayo Takahashi, Kazuhiro Hikima, Hiroyuki Muto, Atsunori Matsuda*, Hetero-Coating of Spherical Graphite with Sulfide Solid Electrolytes via the SEED Process for All-Solid-State Lithium Batteries, Journal of the Ceramic Society of Japan, 133[9] 569-576 (2025), DOI: 10.2109/jcersj2.25056.
[5] Radian Febi Indrawan, Kazuhiro Hikima, and Atsunori Matsuda*, Classification and Analysis of Halide Mixtures in Li10P3S12M (M = Cl, Br, I) Solid Electrolytes for Superionic Conductors, ACS Applied Materials & Interfaces, 16, 66066-66076, (2024), DOI: 10.1021/acsami.4c13428.
[6] Kazuhiro Hikima*, Maro Nishimoto, and Atsunori Matsuda*, Electrochemical Properties and Microstructural Analysis of the Li2FeSO Cathode Material, ACS Applied Energy Materials, 7, 9216-9222, (2024), DOI: 10.1021/acsaem.4c01448.
[7] Reiko Matsuda, Irine Yunhafita Malya, Takuya Matsushita, Kazuhiro Hikima, Atsunori Matsuda*, Fabricating self-standing argyrodite electrolyte sheets containing SiO2 fibers for all-solid-state batteries, Solid State Ionics, 417, 116684 (2024), DOI: 10.1016/j.ssi.2024.116684.
[8] Kazuhiro Hikima*, Ryota Kishi, Hirofumi Tsukasaki, Shigeo Mori, Hiroyuki Muto, and Atsunori Matsuda*, Electrochemical Properties of Li10GeP2S12 Solid Electrolytes Synthesized Using a Solution-Based Method, ACS Applied Energy Materials, 7, 8788−8796, (2024), DOI: 10.1021/acsaem.4c01759.
[9] Keiichiro Maegawa, Hayata Okamoto, Kazuhiro Hikima, Go Kawamura, Atsushi Nagai, Atsunori Matsuda*, Bottom-up synthesis of ion-pair-bridged metal-organic framework for H+ conduction, Chemical Communications, 60, 6925-6928, (2024), DOI: 10.1039/D4CC01706D.
[10] Akira Miura*, Koki Muraoka*. Kotaro Maki, Saori Kawaguchi, Kazuhiro Hikima, Hiroyuki Muto, Atsunori Matsuda, Ichiro Yamane, Toshihiro Shimada, Hiroaki Ito, Yoshikazu Mizuguchi, Chikako Moriyoshi, Hiroshi Nakajima, Shigeo Mori, Hiroshi Oike, Akira Nakayama, Wenhao Sun, Nataly Carolina Rosero-Navarro, Kiyoharu Tadanaga, Stress-Induced Martensitic Transformation in Na3YCl6, Journal of the American Chemical Society, 146, 25263–25269, (2024), DOI: 10.1021/jacs.4c09476.
[11] Tong Fang, Kazuhiro Hikima, Hiroyuki Muto, Atsunori Matsuda, Yuta Fujii, Akira Miura and Kiyoharu Tadanaga*, Inorganic-Organic Hybrid Sulfide Solid Electrolytes Based on the Tetraalkylammonium Iodide-LiI-Li2S-P2S5 System, Journal of The Electrochemical Society, 171, 100522, (2024), DOI: 10.1149/1945-7111/ad8481.
[12] Kazuhiro Hikima*, Kaito Ogawa, Radian Febi Indrawan, Hirofumi Tsukasaki, Satoshi Hiroi, Koji Ohara, Kazutaka Ikeda, Toshiki Watanabe, Toshiyuki Matsunaga, Kentaro Yamamoto, Shigeo Mori, Yoshiharu Uchimoto, Atsunori Matsuda*, Structure and particle surface analysis of Li2S–P2S5–LiI-type solid electrolytes synthesized by liquid-phase shaking, Journal of Solid State Electrochemistry, (2024), DOI: 10.1149/1945-7111/ad8481.
[13] Hanseul Kim, Kazuhiro Hikima, Kenta Watanabe, Naoki Matsui, Kota Suzuki, Satoshi Obokata, Hiroyuki Muto, Atsunori Matsuda, Ryoji Kanno, Masaaki Hirayama*, Mechanical Properties of Li10.35Ge1.35P1.65S12 with Different Particle Sizes, Materials Transactions, 65, 861-866 (2024), DOI: 10.2320/matertrans.MT-Y2024001.
[14] Kazuhiro Hikima*, Yosuke Hamasaki, Masayo Takahashi, Reiko Matsuda, Hiroyuki Muto, Atsunori Matsuda*, Electrochemical and microstructural analysis of LiNi1/3Mn1/3Co1/3O2 cathode composites prepared using the SEED method, Chemical Communications, 60, 6813-6816, (2024), DOI: 10.1039/d4cc02113d.
[15] Kento Ishii, Atsushi Yokoi, Yusaku Sato, Kazuhiro Hikima, Go Kawamura, Wai Kian Tan, Hiroyuki Muto, Atsunori Matsuda, Tetsuo Uchikoshi, Masayoshi Fuji*, Design of highly-sinterable LATP-CNT composite powder by sequential particle assembly for fabrication of highly electrical-conductive composite electrodes, Advanced Powder Technology, 35, 104430, (2024), DOI: 10.1016/j.apt.2024.104430.
[16] Atsunori Matsuda, Kazuhiro Hikima*, Preparation of Lithium Sulfide-Based Cathode Materials and Application to All-Solid-State Batteries, Journal of the Japan Society of Powder and Powder Metallurgy, 71, 75-80, (2024), DOI: 10.2497/jjspm.23-00053.
[17] Hirotada Gamo, Kazuhiro Hikima, and Atsunori Matsuda*, Transition-Metal Sulfides for High-Performance Lithium Sulfide Cathodes in All-Solid-State Lithium–Sulfur Batteries, ACS Omega, 8, 45557-45565, (2023), DOI: 10.1021/acsomega.3c05635.
[18] Radian Febi Indrawan, Reiko Matsuda, Kazuhiro Hikima, Atsunori Matsuda*, Enhanced electrochemistry stability of oxygen doped Li6PS5Cl argyrodite solid electrolyte by liquid-phase synthesis, Solid State Ionics, 401, 116344, (2023), DOI: 10.1016/j.ssi.2023.116344.
[19] Towa Bunno, Keiichiro Maegawa, Mateusz Wlazło, Kazuhiro Hikima, Atsushi Nagai, and Atsunori Matsuda*, Ternary Triazole-Based Organic–Inorganic Proton-Conducting Hybrids Based on Computational Models for HT-PEMFC Application, ACS Omega, 8, 44172–44182, (2023), DOI: 10.1021/acsomega.3c06587.
[20] Keiichiro Maegawa, Mateusz Wlazło, Nguyen Huu Huy Phuc, Kazuhiro Hikima, Go Kawamura, Atsushi Nagai, and Atsunori Matsuda*, Synthesis and Structure-Electrochemical Property Relationships of Hybrid Imidazole-Based Proton Conductors for Medium-Temperature Anhydrous Fuel Cells, Chemistry of Materials, 35, 7708–7718, (2023), DOI: 10.1021/acs.chemmater.3c01482.
[21] Reiko Matsuda, Akihiro Tanaka, Kota Yanagihara, Yoshikazu Sasaki, Kazuhiro Hikima, Hiroyuki Muto, Atsunori Matsuda*, Deterioration Analysis of Si Composite Anodes for All-Solid-State Batteries during Charge–Discharge by Auger Electron Spectroscopy and Scanning Electron Microscopy with Energy Dispersive Spectroscopy, The Journal of Physical Chemistry C, 127, 16508-16514, (2023), DOI: 10.1021/acs.jpcc.3c02935
[22] Kazuhiro Hikima, Yusaku Sato, Atsushi Yokoi, Wai Kian Tan, Hiroyuki Muto, Atsunori Matsuda*, Fabrication and electrochemical properties of electrode composites for oxide-type all-solid-state batteries through electrostatic integrated assembly, Heliyon, 9, e17889, (2023), DOI: 10.1016/j.heliyon.2023.e17889.
[23] Kazuhiro Hikima*, Ryo Fujii, Hirotada Gamo, Hirofumi Tsukasaki, Shigeo Mori, Toshiki Watanabe, Kentaro Yamamoto; Yoshiharu Uchimoto, Hiroyuki Muto, Atsunori Matsuda*, Y2S3-Doped Li2S Active Cathode Materials for All-Solid-State Li–S Batteries, The Journal of Physical Chemistry C, 127, 13511-13517, (2023), DOI: 10.1021/acs.jpcc.3c02144.
[24] Takumi Yabuzaki, Miho Sato, Hanseul Kim, Kenta Watanabe, Naoki Matsui , Kota Suzuki, Satoshi Hori, Kazuhiro Hikima, Satoshi Obokata, Hiroyuki Muto, Atsunori Matsuda, Ryoji Kanno, Masaaki Hirayama*, Electrochemical and mechanical properties and chemical stability of Li10GeP2S12/Al2O3 composite electrolytes, Journal of the Ceramic Society of Japan, 131, 675-684, (2023), DOI: 10.2109/jcersj2.23070.
[25] Kazuhiro Hikima*, Kaito Ogawa, Hirotada Gamo, Atsunori Matsuda*, Li10GeP2S12 solid electrolytes synthesised via liquid-phase methods, Chemical Communications, 59, 6564-6567, (2023), DOI: 10.2109/jcersj2.23070.
[26] Hirotada Gamo*, Ikuyo Kusaba, Kazuhiro Hikima, Atsunori Matsuda*, Rapid solution synthesis of argyrodite-type Li6PS5X (X = Cl, Br, and I) solid electrolytes using excess sulfur, Inorganic chemistry, 62, 6076–6083, (2023), DOI: 10.1021/acs.inorgchem.3c00053.
[27] Keiichiro Maegawa, Yuya Ashida, Kazuhiro Hikima, Wai Kian Tan, Go Kawamura, Atsunori Matsuda*, Enhanced proton conductivity and power density of HT-PEMFCs using tin pyrophosphate microparticles-dispersed polybenzimidazole composite electrolyte membranes, Solid State Ionics, 393, 116186 (9 pages), (2023), DOI: 10.1016/j.ssi.2023.116186.
[28] Keiichiro Maegawa, Kazuhiro Hikima, Wai Kian Tan, Go Kawamura, Hiroyuki Muto, Atsushi Nagai, Andrei Jitianu, Atsunori Matsuda*, Enhancing water uptake and hydroxide ion conductivity of alkali fuel cell electrolyte membrane by layered double hydroxide, Solid State Ionics, 385, 116021(10 pages), (2022), DOI: 10.1016/j.ssi.2022.116021.
[29] Hirotada Gamo*, Kazuhiro Hikima, Atsunori Matsuda*, Understanding decomposition of electrolytes in all-solid-state lithium–sulfur batteries, Chemistry of Materials, 34, 10952-10963, (2022), DOI: 10.1021/acs.chemmater.2c02926.
[30] Hirotada Gamo*, Nguyen Huu Huy Phuc, Mika Ikaria, Kazuhiro Hikima, Hiroyuki Muto, Atsunori Matsuda*, Electrochemical redox of Li2S–CaS and –CaX2(X = Cl, Br, and I) cathode materials for all-solid-state lithium-sulfur batteries, Electrochimica Acta, 431, 141149(8 pages), (2022), DOI: 10.1016/j.electacta.2022.141149.
[31] Nguyen Huu Huy Phuc*, Hirotada Gamo, Kazuhiro Hikima, Hiroyuki Muto, Atsunori Matsuda*, Novel (100-x-y)Li3PS4 ̶ xLiBF4 ̶ yLiCl amorphous solid electrolytes for all ̶ solid ̶ state Li ion battery, Journal of Non-Crystalline Solids, 593, 121768(8 pages), (2022), DOI: 10.1016/j.jnoncrysol.2022.121768.
[32] Hirotada Gamo, Nguyen Huu Huy Phuc*, Mika Ikari, Kazuhiro Hikima, Hiroyuki Muto, Atsunori Matsuda*, Ionic conduction and electric modulus in Li2S–CaS and CaX2 (X = F, Cl, Br, and I) Nanocomposites, Electrochemistry, 90, 67005(7 pages), (2022), DOI: 10.5796/electrochemistry.22-00047.
[33] Kazuhiro Hikima, Keisuke Shimizu, Hisao Kiuchi, Yoyo Hinuma, Kota Suzuki, Masaaki Hirayama, Eiichiro Matsubara, Ryoji Kanno*, Operando analysis of electronic band structure in an all-solid-state thin-film battery, Communications Chemistry, 5, 52 (2022), DOI: 10.1038/s42004-022-00664-w.
[34] Kazuhiro Hikima, Keisuke Shimizu, Hisao Kiuchi, Yoyo Hinuma, Kota Suzuki, Masaaki Hirayama, Eiichiro Matsubara, Ryoji Kanno*, Reaction mechanism of Li2MnO3 electrodes in all-solid-state thin-film battery analyzed by operando hard X-ray photoelectron spectroscopy, Journal of American Chemical Society, 144, 236–247, (2022), DOI: 10.1021/jacs.1c09087.
[35] Kazuhiro Hikima, Mitsuhiro Totani, Satoshi Obokata, Hiroyuki Muto, Atsunori Matsuda*, Mechanical Properties of Sulfide-Type Solid Electrolytes Analyzed Indentation Methods, ACS Applied Energy Materials, 5, 2349–2355, (2022), DOI: 10.1021/acsaem.1c03829.
[36] Kazuhiro Hikima, Ho Jia Ler, Radian Febi Indrawan, Hiroyuki Muto, Atsunori Matsuda*, Li4SiO4 Doped-Li7P2S8I solid electrolytes with high lithium stability synthesised using liquid-phase shaking, RSC Advances, 12(12) 7469-7474, (2022), DOI: 10.1039/d1ra09348g.
[37] Kazuhiro Hikima, Ikuyo Kusaba, Hirotada Gamo, Nguyen Huu Huy Phuc, Hiroyuki Muto, Atsunori Matsuda*, High Ionic Conductivity with Improved Lithium Stability of CaS- and CaI2-Doped Li7P3S11 Solid Electrolytes Synthesized by Liquid-Phase Synthesis, ACS Omega 7(19) 16561-16567 (2022), DOI: 10.1021/acsomega.2c00546.
[38] Kazuhiro Hikima, Kaito Ogawa, Hiroyuki Muto, Atsunori Matsuda*, Li7P2S8I solid electrolytes synthesized by liquid-phase synthesis with improved heat treatment process, Journal of the Ceramic Society of Japan, 130(4) 299-302, (2022), DOI: 10.2109/jcersj2.21176.
[39] Masaya Miura, Kazuhiro Hikima, Atsunori Matsuda*, Fabrication and Electrochemical Characterization of an All-Solid-State Battery with an Anti-Perovskite Electrode Material (Li2Fe)SO, Chemistry Letters, 51, 690-692 (2022), DOI: 10.1246/cl.220123.
[40] Hirotada Gamo*, Jin Nishida, Atsushi Nagai, Kazuhiro Hikima, Atsunori Matsuda*, Solution Processing via Dynamic Sulfide Radical Anions for Sulfide Solid Electrolytes, Advanced Energy and Sustainability Research, 2200019(9pages), (2022), DOI: 10.1002/aesr.202200019.
[41] Hideto Tsuji*, Sena Nogata, Hirotada Gamo, Kazuhiro Hikima, Atsunori Matsuda, Yuki Arakawa, Synthesis, stereocomplex crystallization, homo-crystallization, and thermal properties and degradation of enantiomeric aromatic poly(lactic acid)s, poly(mandelic acid)s, Polymer Degradation and Stability 195, (2022), DOI: 10.1016/j.polymdegradstab.2021.109803.
[42] Nguyen H. H. Phuc, Hirotada Gamo, Kazuhiro Hikima, Hiroyuki Muto, Atsunori Matsuda*, Preparation of CaI2-Doped Li7P3S11 by Liquid-Phase Synthesis and Its Application in an All-Solid-State Battery with a Graphite Anode, ENERGY & FUELS, 36(8) 4577-4584, (2022), DOI: 10.1021/acs.energyfuels.2c00288.
[43] Hirotada Gamo, Takaki Maeda, Kazuhiro Hikima, Minako Deguchi, Yushi Fujita, Yusuke Kawasaki, Atsushi Sakuda, Hiroyuki Muto, Nguyen Huu Huy Phuc, Akitoshi Hayashi, Masahiro Tatsumisago, Atsunori Matsuda*, Synthesis of an AlI3-doped Li2S positive electrode with superior performance in all-solid-state batteries, Material Advances, 3(5) 2488-2494, (2022), DOI: 10.1039/d1ma01228b.
[44] Kazuhiro Hikima, Yoyo Hinuma, Keisuke Shimizu, Kota Suzuki, Sou Taminato, Masaaki Hirayama, Takuya Masuda, Kazuhisa Tamura, Ryoji Kanno*, Reactions of the Li2MnO3 Cathode in an All-Solid-State Thin-Film Battery during Cycling, ACS Applied Materials & Interfaces 13(6) 7650-7663 (2021), DOI: 10.1021/acsami.0c18030.
[45] Kazuhiro Hikima, Nguyen Huu Huy Phuc, Atsunori Matsuda*, Synthesis of 3Li2S–1P2S5–xLiI solid electrolytes by liquid-phase shaking method for all-solid-state Li metal batteries, Journal of Sol-Gel Science and Technology, (2021), DOI: 10.1007/s10971-021-05625-8.
[46] Nguyen Huu Huy Phuc, Kazuhiro Hikima, Hiroyuki Muto, Atsunori Matsuda*, Recent developments in materials design for all-solid-state Li–S batteries, Critical Reviews in Solid State and Materials Sciences, 1-26, (2021), DOI: 10.1080/10408436.2021.1886045.

2. 査読付日本語原著論文
[1] 岸 遼太, 引間 和浩, 松田 厚範*, 液相法による高イオン伝導性 Li10GeP2S12型固体電解質の合成条件検討, 粉体および粉末冶金, 72, 137-141 (2025), DOI: 10.2497/jjspm.25-00011.
[2] Hanseul KIM, 引間 和浩, 渡邊 健太, 松井 直喜, 鈴木 耕太, 小保方 聡, 武藤 浩行, 松田 厚範, 菅野 了次, 平山 雅章*, 硫化物固体電解質Li10.35Ge1.35P1.65S12の微細化による機械的強度の向上, 粉体および粉末冶金, 71, 92-97 (2024), DOI: 10.2497/jjspm.23-00050
[3] 丸山 拓, 引間 和浩, 岸本 治夫, 堀田 照久, 山地 克彦, 山﨑 淳司*, Mn置換したアパタイト型ランタンシリケートにおける結晶相と電気伝導度, 燃料電池, 燃料電池開発情報センター(FCDIC), 14, 79-84 (2014), DOI: https://www.fcdic.jp/pdf/toukouronbun/toukou08.pdf.

3. 著書・訳書
[1] 櫻井 庸司, 稲田 亮史, 東城 友都, 引間 和浩, 松田 厚範, 武藤 浩行, リチウムイオン電池・全固体電池の材料技術 : プロセス・評価技術まで, 科学技術出版, (2021).
・佐野賞(進歩賞), 電気化学会, 2026年3月.
・研究活動表彰(若手賞), 豊橋技術科学大学, 2025年3月.
・研究活動表彰(若手賞), 豊橋技術科学大学, 2024年3月.
・田川記念固体化学奨励賞, 電気化学会 固体化学の新しい指針を探る研究会, 2024年2月.
・2022年度若手研究者特別賞(ECS日本支部助成) 電気化学会東海支部, 2023年2月.
・優秀ポスター発表賞, 日本セラミックス協会2022年年会, 2022年5月.
・Excellent Poster Award, 16th Asian Conference of Solid State Ionics, 2018年9月.
・東京工業大学 物質電子化学専攻 修士論文発表会, 電化賞, 2016年3月.
・第5回 CSJ化学フェスタ, 優秀ポスター発表賞, 2015年11月.
・電気化学会 学生ポスター発表優秀賞, 2014年3月.
・第9回新エネルギー技術シンポジウム 学生ポスター発表優秀賞, 2014年3月.
2026年4月 - 現在:日本セラミックス協会 基礎科学部会, 部会長付幹事(事務局)
2026年4月 - 現在:電気化学会 電気化学誌編集委員会 委員
2026年4月 - 現在:第67回電池討論会 実行委員
2025年4月 - 2025年3月:第66回電池討論会 実行委員
2024年4月 - 2026年3月:日本セラミックス協会 東海支部, 東海若手セラミスト懇話会
2021年2月 - 現在:電気化学会, 電池技術委員会 委員
2019年11月 - 2020年12月:電気化学会, 第61回電池討論会実行委員会 委員
2019年9月 - 2020年3月:電気化学会, 電気化学会第87回大会 大会実行委員

所属学会:
電気化学会
セラミックス協会
粉体粉末冶金協会
固体イオニクス学会
日本化学会
2026年4月〜 豊橋技術科学大学 工学部 電気・電子情報工学系 客員准教授
  • エネルギーデバイス化学講究Ⅱ
  • 組織再編前旧課程の同時開講科目等が含まれており、掲載されている全ての科目を開講するわけではありません。

連絡先

研究室

梶原研究室(9号館246室)

オフィスアワー

月曜日 10:30-12:00

内線番号

内線4861

メールアドレス

khikima●tmu.ac.jp
(メールを送信される場合は●を@に変換してください)