教員イメージ
ISHIDA Masatoshi
准教授

石田 真敏 イシダ マサトシ いしだ まさとし

プロフィール

所属

東京都立大学理学部 化学科
理学研究科 化学専攻

最終学歴・学位

九州大学大学院理学府分子科学専攻・理学(博士)

専門・研究分野

錯体化学・色素材料化学

研究

研究テーマ

近赤外光を活用する光機能性分子の設計と創製
特異な芳香族・反芳香族電子構造の有する分子の創製

研究キーワード

近赤外光色素、ポルフィリン、金属錯体、光熱変換、がん治療

研究イメージ

詳細情報

Antiaromatic Sapphyrin Isomer: Transformation into Contracted Porphyrinoids with Variable Aromaticity, Q. Li*, M. Ishida, Y. Wang, C. Li, G. Baryshnikov, B. Zhu, F. Sha, X. Wu, H. Ågren, H. Furuta*, Y. Xie*, Angew. Chem. Int. Ed. 2022, 62, e202212174.
Selective hetero-bis-metalation of a cisoid isomer of doubly N-confused dioxohexaphyrin, K. Shimomura, Y. Nakamura, H. Kai, K. Saito, K. Furukawa, S. Mori, M. Ishida*, H. Furuta*, J. Porphyrins Phthalocyanines, 2022, 26, 807-814. (Award Article)
Iridium Complex of N-Fused Bilatrienone: Oxidative Cleavage of N-Fused Porphyrin Induced by Iridium–Cyclooctadiene Complexation
J. A. Abraham, S. Mori, M. Ishida*, and H. Furuta*
Chem. Eur. J. 2021, 27, 8268. 
Chiral Interlocked Corrole Dimers Directly Linked at Inner Carbon Atoms of Confused Pyrrole Rings
Y. K. Maurya, P. Wei, T. Shimada, K. Yamasumi, S. Mori, K. Furukawa, H. Kusaba, T. Ishihara, Y. Xie, M. Ishida*, and H. Furuta*
Chem. Asian. J. 2021, 16, 743. (Invited issue)
Expanded N-Confused Phlorin: A Platform for Multiply Fused Polycyclic Ring System via Oxidation within the Macrocycle
C. Li, Q. Li, J. Shao, Z. Tong, M. Ishida, G. Baryshnikov, H. Ågren, H. Furuta,* and Y. Xie*
J. Am. Chem. Soc. 2020, 142, 17195.
Synthesis of Helically π-Extended N-Confused Porphyrin Dimer via meso-Bipyrrole-Bridge with Near-Infrared-II Absorption Capability
K. Yamasumi, Y. Notsuka, Y. Yamaoka, S. Mori, M. Ishida,* and H. Furuta*
Chem. Eur. J. 2020, 26, 13590.
Near-Infrared-III Absorbing and Emitting Dyes: Energy Gap Engineering of Expanded Porphyrinoids via Metallation
Y. Wang, K. Ogasahara, D. Tomihama, R. Mysliborski, M. Ishida,* Y. Hong, Y. Notsuka, Y. Yamaoka, T. Murayama, A. Muranaka, M. Uchiyama, S. Mori, Y. Yasutake, S. Fukatsu, D. Kim,* and H. Furuta*
Angew. Chem. Int. Ed. 2020, 59, 16161. 
Copper 1,19-Diaza-21,24-Dicarbacorrole: A Corrole Analog with an NN Linkage Stabilizes Ground-State Singlet Organocopper Species
B. Biju, I. Hashiguchi, M. Shigeki, S. Shimizu, M. Ishida,* and H. Furuta*
Angew. Chem. Int. Ed. 2020, 59, 15897. 
Synthesis of a Black Dye with Absorption Capabilities Across the Visible-to-Near-Infrared Region: A MO-Mixing Approach via Heterometal Coordination of Expanded Porphyrinoid
Y. Wang H. Kai, M. Ishida*, S. Gokulnath, S. Mori, T. Murayama, A. Muranaka, M. Uchiyama, Y. Yasutake, S. Fukatsu, Y. Notsuka, Y. Yamaoka, M. Hanafusa, M. Yoshizawa*, G. Kim, D. Kim*, and H. Furuta*
J. Am. Chem. Soc. 2020, 142, 6807.
Bis-Metal Complexes of Doubly N-Confused Dioxohexaphyrin as Potential Near Infrared-II Photoacoustic Dyes
K. Shimomura, H. Kai, Y. Nakamura, Y. Hong, S. Mori, K. Miki, K. Ohe, Y. Notsuka, Y. Yamaoka, M. Ishida*, D. Kim*, and H. Furuta*
J. Am. Chem. Soc. 2020, 142, 4429.
Tungsten(VI) Complex of N-Fused Porphyrin Absorbing Near-Infrared Light beyond 1000 nm
T. Yamamoto, J. A. Abraham, S. Mori, M. Toganoh, S. Shimizu, M. Ishida*, and H. Furuta*
Chem. Asian. J. 2020, 15, 748. (Invited issue)
Tripyrrin-Armed Isosmaragdyrins: Synthesis, Heterodinuclear Coordination, and Protonation-Triggered Helical Inversion
C. Li, K. Zhang, M. Ishida, Q. Li, K. Shimomura, G. Baryshnikov, X. Li, M. Savage, X.-Y. Wu, S. Yang, H. Furuta,* and Y. Xie*
Chem. Sci. 2020, 11, 2790.
N-Confused Phlorin-Prodigiosin Chimera: meso-Aryl Oxidation and π-Extension Triggered by Peripheral Coordination
G. Su, Q. Li, M. Ishida, C. Li, F. Sha, X.-Y. Wu, L. Wang, G. Baryshnikov, D. Li, H. Ågren, H. Furuta,* and Y. Xie*
Angew. Chem. Int. Ed. 2020, 59, 1537.
Regioselectively Halogenated Expanded Porphyrinoids as Building Blocks for Constructing Porphyrin–Porphyrinoid Heterodyads with Tunable Energy Transfer
Q. Li, C. Li, J. Kim, M. Ishida, X. Li, T. Gu, X. Liang, W. Zhu, H. Ågren, D. Kim,* H. Furuta,* and Y. Xie*
J. Am. Chem. Soc. 2019, 141, 5294.
Skeletal Rearrangement of Twisted Thia-Norhexaphyrin: Multiply-Annulated Polypyrrolic Aromatic Macrocycles
Q. Li, M. Ishida, H. Kai, T. Gu, C. Li, X. Li, G. Baryshnikov, X. Liang, W. Zhu, H. Ågren, H. Furuta,* and Y. Xie*
Angew. Chem. Int. Ed. 2019, 58, 5925.
Ground-State Copper(III) Stabilized by N-Confused/N-Linked Corroles: Synthesis, Characterization, and Redox Reactivity
Y. K. Maurya, K. Noda, K. Yamasumi, S. Mori, T. Uchiyama, K. Kamitani, T. Hirai, K. Ninomiya, M. Nishibori, Y. Hori, Y. Shiota, K. Yoshizawa, M. Ishida,* and H. Furuta*
J. Am. Chem. Soc. 2018, 140, 6883.
Switch-ON Near IR Fluorescent Dye Upon Protonation: Helically Twisted Bis(Boron Difluoride) Complex of π-Extended Corrorin
Y. Hisamune, T. Kim, K. Nishimura, M. Ishida,* M. Toganoh, S. Mori, D. Kim,* and H. Furuta*
Chem. Eur. J. 2018, 24, 4628.
Doubly N-Confused [36]Octaphyrin(1.1.1.1.1.1.1.1): Isomerization, Bis-Metal Coordination, and Topological Chirality
K. Mitsuno, T. Yoshino, I. Gupta, S. Mori, S. Karasawa, M. Ishida,* and H. Furuta*
Angew. Chem. Int. Ed. 2017, 56, 14252.
Bis-Copper(II)/π-Radical Multi-Heterospin System with Non-innocent Doubly N-Confused Dioxohexaphyrin(1.1.1.1.1.0) Ligand
K. Yamasumi, K. Nishimura, Y. Hisamune, Y. Nagae, T. Uchiyama, K. Kamitani, T. Hirai, M. Nishibori, S. Mori, S. Karasawa, T. Kato, K. Furukawa, M. Ishida,* and H. Furuta*
Chem. Eur. J. 2017, 23, 15322.
Structural, Photophysical, and Magnetic Circular Dichroism Studies of Three Rigidified meso-Pentafluorophenyl-substituted Hexaphyrin Analogues
M. Ishida, T. Furuyama, J. M. Lim, S. Lee, Z. Zhang, S. K. Ghosh, V. M. Lynch, C.-H. Lee,* N. Kobayashi,* D. Kim,* and J. L. Sessler*
Chem. Eur. J. 2017, 23, 6682.
Boron Difluoride Complexes of Expanded N-Confused Calix[n]phyrins That Demonstrate Unique Luminescent and Lasing Properties
M. Ishida, T. Omagari, R. Hirosawa, K. Jono, Y. M. Sung, Y. Yasutake, H. Uno, M. Toganoh, H. Nakanotani, S. Fukatsu,* D. Kim,* and H. Furuta*
Angew. Chem. Int. Ed. 2016, 55, 12045. (Highlighted by Synfacts)
Formation of Ground State Triplet Diradicals from Annulated Rosarin Derivatives by Triprotonation
S. Fukuzumi,* K. Ohkubo, M. Ishida, C. Preihs, B. Chen, W. T. Borden,* D. Kim,* and J. L. Sessler*
J. Am. Chem. Soc. 2015, 137, 9780.
Stable π Radical from a Contracted Doubly N-Confused Hexaphyrin by Double Palladium Metalation
Y. Hisamune, K. Nishimura, K. Isakari, M. Ishida, S. Mori, S. Karasawa, T. Kato, S. Lee, D. Kim,* and H. Furuta*
Angew. Chem. Int. Ed. 2015, 54, 7323.
β-Functionalized Push-Pull Porphyrin Sensitizers in Dye-sensitized Solar Cells: π-Conjugated Spacer Effect
M. Ishida, D. Hwang, Z. Zhang, Y. J. Choi, J. Oh, V. M. Lynch, D. Y. Kim, J. L. Sessler,* and D. Kim*
ChemSusChem 2015, 8, 2967.
Doubly N-Confused Isophlorin: Synthesis, Structure, Copper Coordination
J. Yan, M. Takakusaki, Y. Yang, S. Mori, B. Zhang, Y. Feng, M. Ishida, and H. Furuta*
Chem. Commun. 2014, 50, 14593.
Long-Lived Charge-Separated States Produced in Supramolecular Complexes between Anionic and Cationic Porphyrins
N. L. Bill, M. Ishida, Y. Kawashima, K. Ohkubo, Y. M. Sung, V. Lynch, J. M. Lim, D. Kim,* J. Sessler,* and S. Fukuzumi*
Chem. Sci. 2014, 5, 3888.
Cyclo[6]pyridine[6]pyrrole: A Dynamic, Twisted Mcrocycle with no Meso Bridges
Z. Zhang, W.-Y. Cha, N. Williams, E. Rush, M. Ishida,* V. Lynch, D. Km,* and J. L. Sessler*
J. Am. Chem. Soc. 2014, 136, 7591.
A Hybrid Macrocycle with a Pyridine Subunit Displays Aromatic Character upon Uranyl Cation Complexation
I.-T. Ho, Z. Zhang, M. Ishida,* V. Lynch, W.-Y. Cha, Y. M. Sung, D. Kim,* and J. L. Sessler*
J. Am. Chem. Soc. 2014, 136, 4281.
β-(Ethynylbenzoic acid)-substituted Push-Pull Porphyrins: DSSC Dyes by a Direct Palladium-catalyzed Alkynylation Reaction
M. Ishida, D. Hwang, Y. B. Koo, J. Sung, D. Y. Kim, J. L Sessler*, and D. Kim*
Chem. Commun. 2013, 49, 9164.
Benzimidazole-embedded N-fused Aza-indacenes: Synthesis and Deprotonation-assisted Optical Detection of Carbon Dioxide
M. Ishida, P. Kim, J. Y. Choi, J. Yoon,* D. Kim,* and J. L Sessler*
Chem. Commun. 2013, 49, 6950−6952.

Book Chapter
Novel π-Conjugated Systems Based on N-Confused Porphyrinoids, M. Ishida and H. Furuta
In Chemical Science of pi-Electron Systems (Eds. K. Akasaka, A. Osuka, S. Fukuzumi, H. Kandori, Y. Aso), Springer (Tokyo), 2015, pp. 201−221.

Review
Functionalised Tetrathiafulvalene- (TTF-) Macrocycles: Recent Trends in Applied Supramolecular Chemistry
A. Jana, S. Bähring, M. Ishida, S. Goeb, D. Canevet, M. Sallé,* J. O. Jeppesen,* and J. L. Sessler*
Chem. Soc. Rev. 2018, 47, 5614. (Front Cover)
Tetrathiafulvalene- (TTF-) Derived Oligopyrrolic Macrocycles
A. Jana, M. Ishida, J. S. Park, S. Bähring, J. O. Jeppesen,* and J. L. Sessler*
Chem. Rev. 2017, 117, 2641. (Front Cover)
2022年7月 SPP/JPP Young Investigator Award (ICPP12)
2021年2月 令和2年度コニカミノルタ画像科学奨励賞(優秀賞)、
2020年12月 第39回有機合成化学奨励賞 有機合成化学協会 、
2019年4月 第10回丸山研究奨励賞 、
2019年3月第33回若い世代の特別講演証 日本化学会 、
2015年11月 優秀論文賞 有機合成化学協会九州山口支部
日本化学会、アメリカ化学会、錯体化学会、有機合成化学協会、基礎有機化学会、ポルフィリン・フタロシアニン学会
第7回「福岡万有シンポジウム三地区若手交歓会福岡ミニシンポジウム」世話人、
第28 回基礎有機化学討論会 実行委員、
構造有機化学若手シンポジウム2015 世話人、
第28 回万有福岡シンポジウム 実行委員、
第4 回九州沖縄支部錯体化学若手の会 世話人
  • 基礎ゼミナール
  • 無機化学各論II
  • 化学セミナー
  • 化学特別セミナーI
  • 化学特別セミナーII
  • 化学特別セミナーIII
  • 化学特別セミナーIV
  • 化学特別講義Ⅱ(機能材料化学)
  • 化学特別講義Ⅱ(機能材料化学)
  • 化学特別セミナーII
  • 化学特別セミナーI
  • 化学特別セミナーIV
  • 化学特別セミナーIII
  • 組織再編前旧課程の同時開講科目等が含まれており、掲載されている全ての科目を開講するわけではありません。

連絡先

研究室

8号館348号室

オフィスアワー

オフィスアワーは特に設定しませんが、直接質問したい場合は随時受付しますので、事前にメールでアポイントメントをとってください。

内線番号

内線3433

メールアドレス

ishidam●tmu.ac.jp
(メールを送信される場合は●を@に変換してください)