教員イメージ
MUNAKATA Hirokazu
助教

棟方 裕一 ムナカタ ヒロカズ むなかた ひろかず

プロフィール

所属

東京都立大学都市環境学部 環境応用化学科
都市環境科学研究科 環境応用化学域

最終学歴・学位

大阪大学・博士(工学)

専門・研究分野

電気化学、材料化学

研究

研究テーマ

エネルギーの有効利用に向けて、リチウム二次電池や燃料電池に代表される電気化学エネルギー変換デバイスの高性能化に取り組んでいます。電極や電解質といった構成材料の設計から、それらを有効に活用するための電池の設計まで、構造化をキーワードに研究を行い、二酸化炭素排出量の削減に取り組んでいます。

研究キーワード

燃料電池、リチウム二次電池、構造化セラミックス、電気泳動プロセス

研究イメージ

詳細情報

1. “Quantification of the Carbon-Coating Effect on the Interfacial Behavior of Graphite Single Particles”, Orynbassar Mukhan, Ji-Su Yun, Hirokazu Munakata, Kiyoshi Kanamura, and Sung-Soo Kim, ACS Omega, 9 (2024), 4004.
2. “How to Consider the Interfacial Phenomenon in All-Solid-State Batteries? – Quantitative Analysis using µ-Cavity Electrode”, Ji-Su Yun, Orynbassar Mukhan, Woosuk Cho, Ji-Sang Yu, Hirokazu Munakata, Kiyoshi Kanamura, Sung-Soo Kim, Advanced Sustainable Systems, 8 (2023) 2300297.
3. “TSFZ Growth and Anisotropic Ionic Conductivity of Mg-Doped LiCoO2 Single Crystals”, M. Riju Khandaker, Yuki Maruyama, Masanori Nagao, Satoshi Watauchi, Hirokazu Munakata, Kiyoshi Kanamura, Isao Tanaka, Crystal Growth & Design, 23 (2023) 5699-5704.
4. “Digital-Twin-Driven Diagnostics of Crack Propagation in a Single LiNi0.7Mn0.15Co0.15O2 Secondary Particle during Lithium Intercalation”, Jihun Song, Seong-Hyeon Lim, Kyung-Geun Kim, Nurzhan Umirov, Hyobin Lee, Cyril Bubu Dzakpasu, Jaejin Lim, Jieun Nam, Joonam Park, Je-Nam Lee, Hirokazu Munakata, Kiyoshi Kanamura, Sung-Soo Kim, Yong Min Lee, Advanced Energy Materials, 13 (2023) 2004328.
5. “Traveling solvent floating zone growth and anisotropic ionic conductivity of LixLa(1−x)/3TaO3 single crystals”, Most. Umme Salma, Yuki Maruyama, Masanori Nagao, Satoshi Watauchi, Hirokazu Munakata, Kiyoshi Kanamura, Isao Tanaka, Journal of the Ceramic Society of Japan, 131 (2023) 72-76.
6. “Improving the high-rate performance of LCO cathode by metal oxide coating: Evaluation using single particle measurement”, Jik Soo Kim, Seonghyeon Lim, Rahul S. Ingole, Hirokazu Munakata, Sung-Soo Kim, Kiyoshi Kanamura, Journal of Electroanalytical Chemistry, 933 (2023) 117190.
7. “TSFZ Growth and Anisotropic Ionic Conductivity of Zr-doped LiCoO2 Single Crystals”, M. Riju Khandaker, Yuki Maruyama, Masanori Nagao, Satoshi Watauchi, Hirokazu Munakata, Kiyoshi Kanamura, Isao Tanaka, Crystal Growth & Design, 22 (2022) 5624-5628.
8. “Understanding the relationship of electrochemical properties and structure of microstructure-controlled core shell gradient type Ni-rich cathode material by single particle measurement”, Jik SooKim, Seonghyeon Lim, Hirokazu Munakata, Sung-Soo Kim, Kiyoshi Kanamura, Electrochimica Acta, 390 (2021) 138813.
9. “Untuned broadband spiral micro-coils achieve sensitive multi-nuclear NMR TX/RX from microfluidic samples”, Hossein Davoodi, Nurdiana Nordin, Hirokazu Munakata, Jan G. Korvink, Neil MacKinnon, Vlad Badilita, Scientific Reports, 11 (2021) Article number: 7798.
10. “Solid-State Rechargeable Lithium Metal Battery with Li4B4Al3O12Cl-based Water-Resistant Lithium-Ion-Conducting Oxychloride Glass-Ceramic Electrolyte”, Mayu Saito, Hidechika Arima, Mao Shoji, Yota Kizuki, Hirokazu Munakata, Kiyoshi Kanamura, Koichi Kajihara, J. Electrochem. Soc., 168 (2021) 040524.
11. “Effect of Li ions Doping into p-type Semiconductor NiO as a Hole Injection/Transfer Medium in the CO2 Reduction Sensitized/Catalyzed by Zn-porphyrin/Re-complex upon Visible Light Irradiation”, Ryosuke Nakazato, Yoki Kou, Daisuke Yamamoto, Tetsuya Shimada, Tamao Ishida, Shinsuke Takagi, Hirokazu Munakata, Kiyoshi Kanamura, Hiroshi Tachibana, Haruo Inoue, Research on Chemical Intermediates, 47 (2021) 269–285.
12. “LFP/Graphiteリチウムイオン電池の性能および劣化の予測モデルに関する研究”, 橋本 勉, 棟方裕一, 金村聖志, Electrochemistry, 89 (2021) 303-312.
13. “Hybrid Effect of Micro-patterned Lithium Metal and Three Dimensionally Ordered Macroporous Polyimide Separator on the Cycle Performance of Lithium Metal Batteries”, Dohwan Kim, Hirokazu Munakata, Joonam Park, Youngjoon Roh, Dahee Jin, Myung-Hyun Ryou, Kiyoshi Kanamura, and Yong Min Lee, ACS Appl. Energy Mater., 3 (2020) 3721-3727.
14. “Ceramic-Based Flexible Sheet Electrolyte for Li Batteries”, Eric Jianfeng Cheng, Takeshi Kimura, Mao Shoji, Hiroshi Ueda, Hirokazu Munakata, Kiyoshi Kanamura, ACS Appl. Mater. Interfaces, 12 (2020) 10382-10388.
15. “Carbon Coating for Improvements of Electrochemical Properties of Li1.1V0.9O2 Anode Active Materials for Li Secondary Batteries”, Seonghyeon LIM, Hirokazu MUNAKATA, Kiyoshi KANAMURA, Electrochemistry, 88 (2020) 22-27.
16. “Analysis of intrinsic properties of Li4Ti5O12 using single-particle technique”, Nurzhan Umirov, Yuto Yamada, Hirokazu Munakata, Sung-Soo Kim, Kiyoshi Kanamura, J. Electroanal. Chem., 855 (2019) 113514.
17. “3D electrochemical model for a Single Secondary Particle and its application for operando analysis”, Jihun Song, Williams Agyei Appiah, Kim Sung-Soo, Hirokazu Munakata, Kiyoshi Kanamura, Myung-Hyun Ryou, Yong Min Lee, Nano Energy, 62 (2019) 810-817.
18. “Phosphoric Acid Diethylmethylammonium Trifluoromethanesulfonate-Based Electrolytes for Nonhumidified Intermediate Temperature Fuel Cells”, Jie Yu, Shojiro Kikuchi, Hasna Puthen Peediyakkal, Hirokazu Munakata, Kiyoshi Kanamura, ACS Appl. Mater. Interfaces, 11 (2019) 13761-13767.
19. “Scanning electrochemical cell microscopy for visualization and local electrochemical activities of lithium-ion (de) intercalation process in lithium‐ion batteries electrodes”, Akichika Kumatani, Yasufumi Takahashi, Chiho Miura, Hiroki Ida, Hirotaka Inomata, Hitoshi Shiku, Hirokazu Munakata, Kiyoshi Kanamura, Tomokazu Matsue, Surf Interface Anal., 51 (2019) 27-30.
20. “Highly Durable Non-Platinum Catalyst for Protic Ionic Liquid Based Intermediate Temperature PEFCs”, Hasna PUTHEN PEEDIYAKKAL, Jie YU, Hirokazu MUNAKATA, Kiyoshi KANAMURA, Electrochemistry, 87 (2019) 35-46.
21. “Magnesium Storage Performance and Mechanism of 2D-Ultrathin Nanosheet-Assembled Spinel MgIn2S4 Cathode for High-Temperature Mg Batteries”, Yong Zhang, Masashi Konya, Ayaka Kutsuma, Seonghyeon Lim, Toshihiko Mandai, Hirokazu Munakata, Kiyoshi Kanamura, Small, 15 (2019) 1902236.
22. “Investigation of Carbon-coating Effect on the Electrochemical Performance of LiCoPO4 Single Particle”, Yuto YAMADA, Yusaku NODA, Hirokazu MUNAKATA, Shuhei YOSHIDA, Daisuke SHIBATA, Kiyoshi KANAMURA, Electrochemistry, 86 (2018) 145-151.
23. “Multi-dentate phenoxyimine magnesium chloride complex for magnesium battery electrolyte”, Minato Egashira, Kaori Hiratsuka, Kouki Matsubara, Yasuhiro Akita, Hirokazu Munakata, Kiyoshi Kanamura, Materials Today Energy, 9 (2018) 279-284.
24. “Effect of conductive carbon additives on electrochemical performance of LiCoPO4”, Yuta Maeyoshi, Shohei Miyamoto, Hirokazu Munakata, Kiyoshi Kanamura, J. Power Sources, 376 (2018) 18-25.
25. “Li4B4M3O12Cl (M = Al, Ga): an electrochemically stable, lithium-ion-conducting cubic boracite with substituted boron sites”, Koichi Kajihara, Naoto Tezuka, Mao Shoji, Jungo Wakasugi, Hirokazu Munakata, Kiyoshi Kanamura, Bull. Chem. Soc. Jpn., 90 (2017) 1279-1286.
26. “Reduced Polysulfide Shuttle Effect by Using Polyimide Separators with Ionic Liquid-based Electrolytes in Lithium-Sulfur Battery”, Yanqing Wang, Zengqi Zhang, Masaki Haibara, Deye Sun, Xiaodi Ma, Yongcheng Jin, Hirokazu Munakata, Kiyoshi Kanamura, Electrochim. Acta, 255 (2017) 109-117.
27. “Improvement of sintering of Li6.25Al0.25La3Zr2O12 by using pre-heat treatment”, Jungo Wakasugi, Hirokazu Munakata, Kiyoshi Kanamura, Solid State Ionics, 309, (2017) 9-14.
28. “Improvement of rate capability by graphite foam anode for Li secondary batteries”, Sunghyun Lim, Ji-Hyun Kim, Yuto Yamada, Hirokazu Munakata, Young-Seak Lee, Sung-Soo Kim, Kiyoshi Kanamura, J. Power Sources, 355 (2017) 164-170.
29. “High-temperature conductivity measurements of magnesium-ion-conducting solid oxide Mg0.5-x(Zr1-xNbx)2(PO4)3 (x = 0.15) using Mg metal electrode”, Koichi Kajihara, Hayato Nagano, Takaoki Tsujita, Hirokazu Munakata, Kiyoshi Kanamura, J. Electrochem. Soc., 164 (2017) A2183-A2185.
30. “超高解像度電気化学顕微鏡の創成と応用 (Advanced Scanning Electrochemical Microscope System for High-Resolution imaging and Electrochemical Applications) ”, 松岡 涼, 青柳重夫, 松本尚志, 松平昌昭, 高橋康史, 熊谷明哉, 井田大貴, 棟方裕一, 飯田克彦, 珠玖 仁, 金村聖志, 末永智一 (Ryo MATSUOKA Shigeo AOYAGI, Naoshi MATSUMOTO, Masaaki MATSUDAIRA, Yasufumi TAKAHASHI, Akichika KUMATANI, Hiroki IDA, Hirokazu MUNAKATA, Katsuhiko IIDA, Hitoshi SHIKU, Kiyoshi KANAMURA, Tomokazu MATSUE), Electrochemistry, 85 (2017) 319-326.
31. “Enhanced cycle stability of LiCoPO4 by using three-dimensionally ordered macroporous polyimide separator”, Yuta Maeyoshi, Shohei Miyamoto, Hirokazu Munakata, Kiyoshi Kanamura, J. Power Sources, 350 (2017) 103-108.
32. “Effect of Gold Layer on Interface Resistance between Lithium Metal Anode and Li6.25Al0.25La3Zr2O12 Solid Electrolyte”, Jungo Wakasugi, Hirokazu Munakata, Kiyoshi Kanamura, J. Electrochem. Soc., 164 (2017) A1022-A1025.
33. “Thermal Stability of Various Cathode Materials against Li6.25Al0.25La3Zr2O12 Electrolyte”, Jungo WAKASUGI, Hirokazu MUNAKATA, Kiyoshi KANAMURA, Electrochemistry, 85 (2017) 77-81.
34. “Effect of organic additives on characteristics of carbon-coated LiCoPO4 synthesized by hydrothermal method”, Yuta Maeyoshi, Shohei Miyamoto, Yusaku Noda, Hirokazu Munakata, Kiyoshi Kanamura, J. Power Sources, 337 (2017) 92-99.
35. “A key concept of utilization of both non-Grignard magnesium chloride and imide salts for rechargeable Mg battery electrolytes”, Toshihiko Mandai, Yasuhiro Akita, Shunsuke Yagi, Minato Egashira, Hirokazu Munakata, Kiyoshi Kanamura, J. Mater. Chem. A, 5 (2017) 3152-3156.
36. “High-capacity thick cathode with a porous aluminum current collector for lithium secondary batteries”, Hidetoshi Abe, Masaaki Kubota, Miyu Nemoto, Yosuke Masuda, Yuichi Tanaka, Hirokazu Munakata, Kiyoshi Kanamura, J. Power Sources, 334 (2016) 78-85.
37. “Electrochemical evaluation of active materials for lithium ion batteries by one (Single) particle measurement”, Kiyoshi KANAMURA, Yuto YAMADA, Koji ANNAKA, Natsuko NAKATA, Hirokazu MUNAKATA, Electrochemistry, 84 (2016) 759-765.
38. “Synthesis and Evaluation of Microspherical Li1.2Mn0.54Co0.13Ni0.13O2 through Carbon Dioxides-assisted Co-precipitation Method for Lithium-ion Battery”, Wenchao Yan, Jicheng Jiang, Wei Liu, Xiao Yan, Deye Sun, Yongcheng Jin, Jing Wang, Lan Xiang, Hirokazu Munakata, Kiyoshi Kanamura, Electrochim. Acta, 212 (2016) 16-24.
39. “Fabrication of All-Solid-State Lithium-Ion Cells Using Three-Dimensionally Structured Solid Electrolyte Li7La3Zr2O12 Pellets”, Mao Shoji, Hirokazu Munakata, Kiyoshi Kanamura, Front. Energy Res., August 2016 Vol. 4 Article 32.
40. “Good Low-Temperature Properties of Nitrogen-Enriched Porous Carbon as Sulfur Hosts for High-Performance Li-S Batteries”, Shaoyin Zhu, Yanqing Wang, Jicheng Jiang, Xiao Yan, Deye Sun, Yongcheng Jin, Cewen Nan, Hirokazu Munakata, Kiyoshi Kanamura, ACS Appl. Mater. Interfaces, 8 (2016) 17253-17259.
41. “Characterization and Optimization of Silicon Nanoparticle Anodes”, Soichiro KAWAKAMI, Hirokazu MUNAKATA, Yasuhiro AKITA, Kiyoshi KANAMURA, Electrochemistry, 84 (2016) 243-253.
42. “Effect of Anatase TiO2 on Electrochemical Properties of Elongated Bending TiO2-Bronze nanowires for Lithium Ion Batteries”, Xiao Yan, Wei Liu, Wenchao Yan, Deye Sun, Yongcheng Jin, Jing Wang, Lan Xiang, Hirokazu Munakata, Kiyoshi Kanamura, Electrochim. Acta, 191 (2016) 661–668.
43. “Synthesis of nanostructured Ni3S2 with different morphologies as negative electrode materials for lithium ion batteries”, Wenchao Duan, Wenchao Yan, Xiao Yan, Hirokazu Munakata, Yongcheng Jin, Kiyoshi Kanamura, J. Power Sources, 293 (2015) 706-711.
44. “Lithium Diffusion in Cation-Mixing-Free LiMn1-xFexPO4 Synthesized by Hydrothermal Process”, Keigo Hoshina, Tetsuya Sasakawa, Norio Takami, Hirokazu Munakata, Kiyoshi Kanamura, J. Electrochem. Soc., 162 (2015) A2827-A2833.
45. “Mechanical Milling Synthesis and Electrochemical Evaluation of Silicon-transition Metal Alloy Anode Materials for Lithium-ion Batteries”, Soichiro KAWAKAMI, Hiroya KAIDOU, Yasuhiro AKITA, Hirokazu MUNAKATA, Kiyoshi KANAMURA, Electrochemistry, 83 (2015) 445-451.
46. “The influence of the pyrolysis temperature on the electrochemical behavior of carbon-rich SiCN polymer-derived ceramics as anode materials in lithium-ion batteries”, Lukas Mirko Reinold, Yuto Yamada, Magdalena Graczyk-Zajac, Hirokazu Munakata, Kiyoshi Kanamura, Ralf Riedel, J. Power Sources, 282 (2015) 409-415.
47. “Nanoscale visualization of redox activity at lithium-ion battery cathodes”, Yasufumi Takahashi, Akichika Kumatani, Hirokazu Munakata, Hirotaka Inomata, Komachi Ito, Kosuke Ino, Hitoshi Shiku, Patrick R. Unwin, Yuri E. Korchev, Kiyoshi Kanamura, Tomokazu Matsue, Nature Commun., 5 (2014) Article number: 5450.
48. “Preparation and electrochemical properties of Zr-site substituted Li7La3(Zr2−xMx)O12 (M = Ta, Nb) solid electrolytes”, Mian Huang, Mao Shoji, Yang Shen, Ce-Wen Nan, Hirokazu Munakata, Kiyoshi Kanamura, J. Power Sources, 261 (2014) 206-211.
49. “Hydrothermal synthesis of Fe-substituted manganese dioxide and its electrochemical characterization for lithium rechargeable batteries”, Jin-Hee Moon, Hirokazu Munakata, Kiyoshi Kanamura, Electrochim. Acta, 134 (2014) 92-99.
50. “Rapid charge and discharge property of high capacity lithium ion battery applying three-dimensionally patterned electrode”, Akira Izumi, Masakazu Sanada, Koji Furuichi, Kuniko Teraki, Takeshi Matsuda, Kenta Hiramatsu, Hirokazu Munakata, Kiyoshi Kanamura, J. Power Sources, 256 (2014) 244-249.
51. “Solubility and Diffusion Coefficient of Oxygen in Protic Ionic Liquids with Different Fluoroalkyl Chain Lengths”, Masaki Haibara, Syuhei Hashizume, Hirokazu Munakata, Kiyoshi Kanamura, Electrochim. Acta, 132 (2014) 208-213.
52. “Electrochemical Characterization of Phosphorous-doped Soft Carbon using Single Particle for Lithium Battery Anode”, Jeong Eun Chae, Koji Annaka, Kijoo Hong, Sang-Ick Lee, Hirokazu Munakata, Sung-Soo Kim, Kiyoshi Kanamura, Electrochim. Acta, 130 (2014) 60-65.
53. “Formation of Hydroxyapatite on Sodium Titanate-Modified Porous Titanium”, DAORINA, H irokazu MUNAKATA, Kiyoshi KANAMURA, J. Soc. Inorg. Mater., Jpn. 21 (2014) 162-169.
54. “In-situ observation of one silicon particle during the first charging”, Kei Nishikawa, Hirokazu Munakata, Kiyoshi Kanamura, J. Power Sources, 243 (2013) 630-634.
55. “In-situ Fourier transform infrared spectroscopic analysis on dynamic behavior of electrolyte solution on LiFePO4 cathode”, Yasuhiro Akita, Midori Segawa, Hirokazu Munakata, Kiyoshi Kanamura, J. Power Sources, 239 (2013) 175-180.
56. “Design and evaluation of a three dimensionally ordered macroporous structure within a highly patterned cylindrical Sn-Ni electrode for advanced lithium ion batteries”, Yongcheng Jin, Hirokazu Munakata, Naoya Okada, Kiyoshi Kanamura, J. Nanomater., (2013) Article ID 937019.
57. “PHOSPHATE MATERIALS FOR RECHARGEABLE BATTERY APPLICATIONS”, Kiyoshi Kanamura, Hirokazu Munakata, Yusuke Namiki, Phosphorus Res. Bull., 28 (2013) 30-36.
58. “Hydrothermal synthesis of manganese dioxide nanoparticles as cathode material for rechargeable batteries”, Jin-Hee MOON, Hirokazu MUNAKATA, Koichi KAJIHARA, Kiyoshi KANAMURA, Electrochimstry, 81 (2013) 2-6.
59. “Concerted Migration Mechanism in the Li Ion Dynamics of Garnet-Type Li7La3Zr2O12”, Randy Jalem, Yoshihiro Yamamoto, Hiromasa Shiiba, Masanobu Nakayama, Hirokazu Munakata, Toshihiro Kasuga, Kiyoshi Kanamura, Chem. Mater., 25 (2013) 425-430.

文字数制限のため2013年以降のみ掲載
1. 東京都立大学都市環境学部 リーディング・サイエンティスト賞(2024年3月)
2. 首都大学東京都市環境学部 リーディング・サイエンティスト賞(2020年1月)
3. 日本化学会BCSJ賞(vol. 90, no. 12, 2017)
4. 無機リン化学会 30周年記念特別奨励賞(2016年9月)
5. 首都大学東京都市環境学部 リーディング・サイエンティスト賞(2011年10月)
6. 電気化学会 進歩賞・佐野賞(2011年3月)
7. 日本無機リン化学会 若手優秀研究発表賞(2010年10月)
8. 無機マテリアル学会 講演奨励最優秀賞(2009年11月)
日本化学会、電気化学会、高分子学会、日本セラミックス協会、日本エネルギー学会、無機マテリアル学会、日本無機リン化学会、Electrochemical Society
社会のニーズに対応した電池材料や電池技術の開発を進めている。研究会の開催や行政と連携を通して、知的資源を社会に幅広く提供できるよう努めている。2016年度からは水素エネルギー社会構築推進研究センターに参画し、研究開発だけでなく、教育や啓発活動を通して大都市東京における水素社会の実現に取り組んでいる。

日本無機リン化学会 編集委員
燃料電池開発情報センター 編集委員
電気化学会 大会学術企画委員会 委員
電気化学会 普及委員会 委員
日本化学会 化学電池材料研究会 幹事
Review Editor on the Editorial Board of Membrane Applications - Energy (Frontiers in Membrane Science and Technology)
  • Instrumental Techniques for Material Chemistry
  • 組織再編前旧課程の同時開講科目等が含まれており、掲載されている全ての科目を開講するわけではありません。

連絡先

研究室

9号館142号室

オフィスアワー

火 9:30-12:00

内線番号

内線4933

メールアドレス

munakata●tmu.ac.jp
(メールを送信される場合は●を@に変換してください)