教員イメージ
KUBO Yuji
教授

久保 由治 クボ ユウジ くぼ ゆうじ

プロフィール

所属

東京都立大学都市環境学部 環境応用化学科
都市環境科学研究科 環境応用化学域

最終学歴・学位

大阪府立大学大学院工学研究科応用化学専攻博士前期課程修了・工学博士

専門・研究分野

有機化学、超分子化学、光機能性分子化学

研究

研究テーマ

有機合成化学を基盤とするエネルギー関連材料や超分子材料の創製と応用;
1) 有機太陽電池用増感色素の合成と評価
2 太陽光の高効率利用を指向したフォトン・アップコンバージョンの構築
3) 光電変換デバイスへの応用を指向した有機色素の合成
4) 光電気化学セルまたは光触媒を用いた高効率水素製造技術の開発
5) 超分子形成に基づくケモセンサー材料の調製
6) 安心・安全な社会に貢献できる機能材料の開発

研究キーワード

有機合成化学、有機太陽電池、水素製造、π共役分子、色素、超分子、自己組織、分子認識、ケモセンサー、固体発光材料、固体触媒

研究イメージ

詳細情報

科学技術振興事業団個人研究推進事業 「さきがけ研究21」,形とはたらき研究員兼務(1997-2000)

*K. Kawaguchi, N. Sugawara, M. Ito and Y. Kubo, Thermochromic afterglow from benzene 1,4-diboronic acid-doped co-crystals, Chem. Eur. J., 2024, e202303924. DOI: 10.1002/chem.202303924

*R. Hasegawa, M. Ito, and Y. Kubo, Tuning the triplet population of arylselanyl-BODIPY photosensitizers through substituents engineering for triplet-triplet annihilation photon upconversion with perylene, J. Porphyr, Phthalocyanines, 2023, 27, 757–764. DOI: 10.1142/S1088424623500037

*S. Takegawa, M. Ito and Y. Kubo, Turn-on type afterglow probe for Hg2+ sensing by a PVA-mediated triplet sensitizer, New. J. Chem., 2023, 47, 12554–12560. DOI: 10.1039/D3NJ01281F

*K. Kawaguchi, M. Ito and Y. Kubo, Chemometrics-assisted mechanism study of the room-temperature phosphorescence on nanoscopic boronate assemblies, Chem. Commun., 2023, in press. DOI: 10.1039/D2CC07049A

*R. Hasegawa, M. Ito and Y. Kubo, Tuning the triplet population of arylselanyl-BODIPY photosensitizers through substituents engineering for triplet-triplet annihilation photon upconversion with perylene, J. Porphyr. Phthalocyanines, 2022, in press. DOI: 10.1142/S1088424623500037

K. Omasa, M. Ito and Y. Kubo, Zn(II)-coordination-driven chiroptical and emissive sensing for chiral amines using a quaterphenyl-5'-carbaldehyde, New. J. Chem., 2022, 46, 21845–21851. DOI: 10.1039/D2NJ04781K

*A. Koga, K. Kawaguchi, M. C. Maida and Y. Kubo, A ratiometric afterglow response of aluminium ions in methanol-water, Chem. Asian J., 2022, 17, e202200402. DOI: 10.1002/asia.202200402R1

*S. Iwaki, R. Hasegawa, and Y. Kubo, Near-infrared room-temperature phosphorescence in arylmetal BODIPY-doped materials, ChemPhotoChem, 2022, e202200073 . doi.org/10.1002/cptc.202200073

*S. Farshbaf, K. Dey, W. Mochida, M. Kanakubo, R. Nishiyabu, Y. Kubo, and P. Anzenbacher Jr., Detection of phosphates in water utilizing a Eu3+- mediated relay mechanism, New J. Chem., 2022, 46, 1839-1844, DOI: 10.1039/d1nj04578d

*K. Kawaguchi, A. Moro, S. Kojima and Y. Kubo, Chiral recognition coupled with chemometrics using boronate ensembles containing D-π-A cyanostilbenes, Chem. Commun., 2021, 57, 12952-12955. DOI:10.1039/D1CC05492A.

*K. Makino, T. I, and Y. Kubo, A benzofuran[b]-fused BODIPY as an efficient sensitizer for photocatalytic hydrogen production, Sustainable Energy Fuels, 2021, 5, 3676-3686. DOI: 10.1039/D1SE00387A

*M. Pushina, S. Farshbaf, W. Mochida, M. Kanakubo, Ryuhei Nishiyabu, Yuji Kubo, and P. Anzenbacher, Jr., A fluorescence sensor array based on zinc(II)-carboxyamidoquinolines: Toward quantitative detection of ATP, Chem. Eur. J., 2021, 27, 11344-11351. DOI: 10.1002/chem.202100896

*R. Hasegawa, S. Iwakiri, Y. Kubo, Synthesis and triplet sensitization of bis(arylselanyl)BOPHYs; potential application in triplet-triplet annihilation upconversion, New J. Chem., 2021, 45, 6091-6099. DOI: 10.1039/D1NJ00721A

* M. Kanakubo, Y. Yamamoto, Y. Kubo, Room-temperature phosphorescence of thiophene boronate ester-cross linked polyvinyl alcohol; a triplet-to-singlet FRET-induced multi-color afterglow luminescence with Sulforhodamine B, Bull. Chem. Soc. Jpn., Advanced Publication, DOI.org/10.1246/bcsj.20210004

*Y. Kubo, T. Nozawa, K. Maeda, Y. Hashimoto, Asymmetrical benzo[a]-fused N2O2-boron-chelated BODIPYs as red to near-infrared absorbing chromophores: Synthesis, characteristics and device applications for opto-electronics, Mater. Adv., 2021, 2, 1059-1071.DOI: 10.1039/D0MA00910E

* T. Arai, Y. Kubo, Chemical stimulus-responsive tricyanopyrroline-based ICT chromophore as a potential environment-sensitive probe, Dyes and Pigments., 2021, 185, 108927.DOI: 10.1016/j.dyepig.2020.108927

*Y. Sasaki, S. Kojima, V. Hamedpour, R. Kubota, S. Takizawa, I. Yoshikawa, H. Houjou, Y. Kubo and T. Minami, Accurate chiral pattern recognition for amines, albeit a single chemosensor. Chem. Sci., 2020, 11, 3790-3796. DOI: 10.1039/D0SC00194E

*M. Hoshi, R. Nishiyabu, Y. Hayashi, S. Yagi and Y. Kubo, Room-temperature phosphorescence-active boronate particles: characterization and ratiometric afterglow-sensing behavior via surface grafting of Rhodamine B. Chem. Asian J., 2020, 15, 787-795. DOI: 10.1002/asia.201901740

*R. Nishiyabu, Y. Takahashi, T. Yabuki, S. Gommori, Y. Yamamoto, H. Kitagishi and Y. Kubo, Boronate sol–gel method for one-step fabrication of polyvinyl alcohol hydrogel coatings by simple cast- and dip-coating techniques. RSC Adv., 2020, 20, 86-94. DOI: 10.1039/C9RA08208E

*Y. Kubo, T. Shimada, K. Maeda and Y. Hashimoto, Thieno[1,3,2]oxazaborinine-containing aza-BODIPYs with near infrared absorption bands: synthesis, photophysical properties, and device application. New J. Chem., 2020, 44, 29-37. DOI: 10.1039/C9NJ04612G

*Y. Higashino, S. Erten-Ela and Y. Kubo, π-Expanded dibenzo-BODIPY with near-infrared light absorption: investigation of photosensitizing properties of NiO-based p-type dye-sensitized solar cells. Dyes and Pigments, 2019, 170, 107613. DOI: 10.1016/j.dyepig.2019.107613

*O. Suryani, Y. Higashino, H. Sato and Y. Kubo, Visible-to-Near-Infrared Light-Driven Photocatalytic Hydrogen Production Using Dibenzo-BODIPY and Phenothiazine Conjugate as Organic Photosensitizer. ACS Appl. Energy Mater., 2019, 2, 448-458. DOI: 10.1021/acsaem.8b01474

*M. Hoshi, N. Kaneko, R. Nishiyabu and Y. Kubo, Formation of emissive nanoparticles from tetraphenylethylene-containing boronate macrocycles: preparation, characterization and functionalization. J. Mater. Chem. C, 2018, 6, 11052-11062. DOI: 10.1039/C8TC03748E

*M. Nakashima, K. Iizuka, M. Karasawa, K. Ishii and Y. Kubo, Selenium-containing BODIPY dyes as photosensitizers for triplet-triplet annihilation upconversion, J. Mater. Chem. C, 2018, 6, 6208-6215. DOI: 10.1039/C8TC00944A
R. Nishiyabu, M. Tomura, T. Okade, and Y. Kubo, Boronic acids as molecular inks for surface functionalization of polyvinyl alcohol substrates, New J. Chem., 2018, 42, 7392-7398. DOI: 10.1039/C8NJ00992A

* Y. Kubo, S. Tobinaga, Y. Ueno, T. Aotake, H. Yakushiji, and T. Yamamoto, Near-infrared-absorbing Photodetectors based on naphtho[1,3,2]oxazaborinine-type dibenzo-BODIPY dyes, Chem. Lett., 2018, 47, 300-303. DOI: 10.1246/cl.171061

* M. Kawai, A. Hoshi, R. Nishiyabu and Y. Kubo, Fluorescent chirality recognition by simple boronate ensembles with aggregation-induced emission capability, Chem. Commun., 2017, 53, 10144-0147. DOI: 10.1039/C7CC05784A

* S. Erten-Ela, Y. Ueno, T. Asaba and Y. Kubo, Synthesis of a dibenzo-BODIPY-incorporating phenothiazine dye as a panchromatic sensitizer for dye-sensitized solar cells, New. J. Chem., 2017, 41, 10367-10375. DOI: 10.1039/C7NJ01735A

* O. Suryani, Y. Higashino, J. Y. Mulyana, M. Kaneko, T. Hoshi, K. Shigaki and Y. Kubo, Near-infrared organic photosensitizer for use in dye-sensitized photoelectrochemical water splitting, Chem. Commun., 2017, 53, 6784-6787. DOI: 10.1039/C7CC02730C

* K. Sakakibara, Y. Takahashi, R. Nishiyabu and Y. Kubo, A Zn2+-coordinated boronate dipyrrin as a chemodosimeter toward hydrogen peroxide, J. Mater. Chem. C, 2017, 5, 3684-3691. (2017 Journal of Materials Chemistry C HOT Papers) DOi: 10.1039/C7TC00405B

* Y. Satta, R. Nishiyabu, T. D. James and Y. Kubo, A 1-hydroxy-2,3,1-benzodiazaborine-containing π-conjugated system: synthesis, optical properties and solvent-dependent response toward anions, Tetrahedron, 2017, 73, 2053-2061. DOI: 10.1016/j.tet.2017.02.050

* Y. Kubo and R. Nishiyabu, White-light emissive materials based on dynamic polymerization in supramolecular chemistry, Polymer, 2017, 128, 257-275. DOI: 110.1016/j.polymer.2016.12.082

* S. Yamazawa, M. Nakashima, Y. Suda, R. Nishiyabu and Y. Kubo, 2,3-Naphtho-fused BODIPYs as near-infrared absorbing dyes, J. Org. Chem., 2016, 81, 1310-1315. DOI: 10.1021/acs.joc.5b02720

* Y. Kubo, D. Kakizaki, M. Kogo and Y. Magatani, Water-dispersible boronate nanoparticles as support materials for noble metals in the hydrogenation of levulinic acid to γ-valerolactone, Supramol. Chem., 2016, 28, 91-97. DOI: 10.1080/10610278.2015.1086764

* Y. Suda, R. Nishiyabu and Y. Kubo, Multi-thiophene-substituted NIR boron-dibenzopyrromethene dyes: synthesis and their spectral properties, Tetrahedron, 2015, 71, 4174-4182. DOI: 10.1016/j.tet.2015.04.094

* Y. Kubo, R. Nishiyabu and T. D. James, Hierarchical supramolecules and organization using boronic acids building blocks, Chem. Commun., 2015, 51, 2005-2020. DOI: 10.1039/C4CC07712A

* A. Ozawa, A. Shimizu, R. Nishiyabu and Y. Kubo, Thermo-responsive white-light emission based on tetraphenylethylene- and rhodamine B-containing boronate nanoparticles, Chem. Commun., 2015, 51, 118-121. DOI: 10.1039/C4CC07405J (Highlighted by the ACS Noteworthy Chemistry website)

* A. Matsumoto, R. Nishiyabu and Y. Kubo, Synthesis of a borylated boron-dibenzopyrromethene dye enabling the visual detection of H2O2 vapor, RSC Adv., 2014, 4, 37973-37978. DOI: 10.1039/C4RA06061J

* R. Nishiyabu, S. Ushikubo, Y. Kamiya and Y. Kubo, A boronate hydrogel film containing organized two-component dyes as a multicolor fluorescent sensor for heavy metal ions in water, J. Mater. Chem. A, 2014, 2, 15846-15852. DOI: 10.1039/C4TA03268C

* S. Fujiwara, N. Takanashi, R. Nishiyabu and Y. Kubo, Boronate microparticle-supported nano-palladium and nano-gold catalysts for chemoselective hydrogenation of cinnamaldehyde in environmentally preferable solvent, Green. Chem., 2014, 16, 3230-3236. DOI: 10.1039/C4GC00383G

* S. Ozawa, R. Nishiyabu, and Y. Kubo, Nanospherical aggregation of isothiouronium-terminated amphiphilic polythiophene: Preparation and vapor-phase detection of volatile organic compounds, J. Nanosci. Nanotech., 2014, 14, 6624-6631. DOI: 10.1166/jnn.2014.9343

* Y. Kubo, D. Eguchi, A. Matsumoto, R. Nishiyabu, H. Yakushiji, K. Shigaki and M. Kaneko, Boron-dibenzopyrromethene-based organic dyes for application in dye-sensitized solar cells, J. Mater. Chem. A, 2014, 2, 5204-5211. DOI 10.1039/C3TA15340A

* R. Nishiyabu, Y. Sugino, and Y. Kubo, White light emitting boronate microparticles for potential use as reusable bright chemosensors in water, Chem. Commun., 2013, 49, 9869-9871. DOI 10.1039/C3CC45739G

* K. Otsuka, T. Kondo, R. Nishiyabu, and Y. Kubo, Solvent-manipulated guest binding and signaling of a fluorescent resorcin[4]arene cavitand with 1,3,2-benzodiazaboryl D-π-A conjugation flaps, J. Org. Chem., 2013, 78, 5782-5787. DOI 10.1021/jo4006238

* S. D. Bull, M. G. Davidson, J. M. H. van den Elsen, J. S. Fossey, A. T. A. Jenkins, Y.-B. Jiang, Y. Kubo, F. Marken, K. Sakurai, J. Zhao, and T. D. James, Exploiting the reversible covalent bonding of boronic acids: recognition, sensing, and assembly, Acc. Chem. Res., 2013, 46, 312-326. DOI 10.1021/ar300130w

その他
1997年 第12回日本化学会「若い世代の特別講演会証」受賞
1998年 第10回有機合成化学協会東レ研究企画賞
2013年 Daiwa Adrian Prize 2013共同受賞
2015年 平成26年度特別研究員等審査会専門委員(書面担当)表彰(日本学術振興会)
2015年 平成27年度首都大学東京都市環境学部主幹教授表彰
2019年 平成30年度特別研究員等審査会専門委員(書面担当)表彰(日本学術振興会)
日本化学会,アメリカ化学会,高分子学会、有機合成化学協会
国際学術誌「Supramolecular Chemistry」の Editorial Board Member
東京大学生産技術研究所リサーチフェロー兼職
東京薬科大学後援会副会長
企業との共同研究
非常勤講師(早稲田大学大学院理工学術院、山形大学大学院理工学研究科)
高校化学グランドコンテスト審査委員
オープンユニバーシテイの講師
ホスト--ゲスト・超分子化学研究会幹事
  • 基礎ゼミナール
  • 有機物質化学2
  • エネルギー材料化学
  • 有機物質化学2
  • エネルギー材料化学
  • 先端物質デザイン化学講究Ⅰ
  • 先端物質デザイン化学講究Ⅱ
  • 組織再編前旧課程の同時開講科目等が含まれており、掲載されている全ての科目を開講するわけではありません。

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連絡先

研究室

9号館448号室

オフィスアワー

水 13:00-14:30

内線番号

内線4937

メールアドレス

yujik●tmu.ac.jp
(メールを送信される場合は●を@に変換してください)